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Four-dimensional metal-organic frameworks

Author

Listed:
  • Jack D. Evans

    (Technische Universität Dresden)

  • Volodymyr Bon

    (Technische Universität Dresden)

  • Irena Senkovska

    (Technische Universität Dresden)

  • Hui-Chun Lee

    (Technische Universität Dresden)

  • Stefan Kaskel

    (Technische Universität Dresden)

Abstract

Recognising timescale as an adjustable dimension in porous solids provides a new perspective to develop novel four-dimensional framework materials. The deliberate design of three-dimensional porous framework architectures is a developed field; however, the understanding of dynamics in open frameworks leaves a number of key questions unanswered: What factors determine the spatiotemporal evolution of deformable networks? Can we deliberately engineer the response of dynamic materials along a time-axis? How can we engineer energy barriers for the selective recognition of molecules? Answering these questions will require significant methodological development to understand structural dynamics across a range of time and length scales.

Suggested Citation

  • Jack D. Evans & Volodymyr Bon & Irena Senkovska & Hui-Chun Lee & Stefan Kaskel, 2020. "Four-dimensional metal-organic frameworks," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-16527-8
    DOI: 10.1038/s41467-020-16527-8
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    Cited by:

    1. Jabadurai Jayapaul & Sanna Komulainen & Vladimir V. Zhivonitko & Jiří Mareš & Chandan Giri & Kari Rissanen & Perttu Lantto & Ville-Veikko Telkki & Leif Schröder, 2022. "Hyper-CEST NMR of metal organic polyhedral cages reveals hidden diastereomers with diverse guest exchange kinetics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Francesco Walenszus & Volodymyr Bon & Jack D. Evans & Simon Krause & Jürgen Getzschmann & Stefan Kaskel & Muslim Dvoyashkin, 2023. "On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Eunji Jin & In Seong Lee & D. ChangMo Yang & Dohyun Moon & Joohan Nam & Hyeonsoo Cho & Eunyoung Kang & Junghye Lee & Hyuk-Jun Noh & Seung Kyu Min & Wonyoung Choe, 2023. "Origamic metal-organic framework toward mechanical metamaterial," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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