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CO oxidation activity of non-reducible oxide-supported mass-selected few-atom Pt single-clusters

Author

Listed:
  • Atsushi Beniya

    (Toyota Central R&D Labs, Inc.)

  • Shougo Higashi

    (Toyota Central R&D Labs, Inc.)

  • Nobuko Ohba

    (Toyota Central R&D Labs, Inc.)

  • Ryosuke Jinnouchi

    (Toyota Central R&D Labs, Inc.)

  • Hirohito Hirata

    (Toyota Motor Corporation)

  • Yoshihide Watanabe

    (Toyota Central R&D Labs, Inc.)

Abstract

Platinum nanocatalysts play critical roles in CO oxidation, an important catalytic conversion process. As the catalyst size decreases, the influence of the support material on catalysis increases which can alter the chemical states of Pt atoms in contact with the support. Herein, we demonstrate that under-coordinated Pt atoms at the edges of the first cluster layer are rendered cationic by direct contact with the Al2O3 support, which affects the overall CO oxidation activity. The ratio of neutral to cationic Pt atoms in the Pt nanocluster is strongly correlated with the CO oxidation activity, but no correlation exists with the total surface area of surface-exposed Pt atoms. The low oxygen affinity of cationic Pt atoms explains this counterintuitive result. Using this relationship and our modified bond-additivity method, which only requires the catalyst–support bond energy as input, we successfully predict the CO oxidation activities of various sized Pt clusters on TiO2.

Suggested Citation

  • Atsushi Beniya & Shougo Higashi & Nobuko Ohba & Ryosuke Jinnouchi & Hirohito Hirata & Yoshihide Watanabe, 2020. "CO oxidation activity of non-reducible oxide-supported mass-selected few-atom Pt single-clusters," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-15850-4
    DOI: 10.1038/s41467-020-15850-4
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    Cited by:

    1. Tengfei Zhang & Peng Zheng & Jiajian Gao & Xiaolong Liu & Yongjun Ji & Junbo Tian & Yang Zou & Zhiyi Sun & Qiao Hu & Guokang Chen & Wenxing Chen & Xi Liu & Ziyi Zhong & Guangwen Xu & Tingyu Zhu & Fabi, 2024. "Simultaneously activating molecular oxygen and surface lattice oxygen on Pt/TiO2 for low-temperature CO oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Taek-Seung Kim & Christopher R. O’Connor & Christian Reece, 2024. "Interrogating site dependent kinetics over SiO2-supported Pt nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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