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Probing the energy conversion process in piezoelectric-driven electrochemical self-charging supercapacitor power cell using piezoelectrochemical spectroscopy

Author

Listed:
  • Karthikeyan Krishnamoorthy

    (Jeju National University)

  • Parthiban Pazhamalai

    (Jeju National University)

  • Vimal Kumar Mariappan

    (Jeju National University)

  • Swapnil Shital Nardekar

    (Jeju National University)

  • Surjit Sahoo

    (Jeju National University)

  • Sang-Jae Kim

    (Jeju National University
    Jeju National University)

Abstract

The design and development of self-charging supercapacitor power cells are rapidly gaining interest due to their ability to convert and store energy in an integrated device. Here, we have demonstrated the fabrication of a self-charging supercapacitor using siloxene sheets as electrodes and siloxene-based polymeric piezofiber separator immobilized with an ionogel electrolyte. The self-charging properties of the fabricated device subjected to various levels of compressive forces showed their ability to self-charge up to a maximum of 207 mV. The mechanism of self-charging process in the fabricated device is discussed via “piezoelectrochemical effect” with the aid of piezoelectrochemical spectroscopy measurements. These studies revealed the direct evidence of the piezoelectrochemical phenomenon involved in the energy conversion and storage process in the fabricated device. This study can provide insight towards understanding the energy conversion process in self-charging supercapacitors, which is of significance considering the state of the art of piezoelectric driven self-charging supercapacitors.

Suggested Citation

  • Karthikeyan Krishnamoorthy & Parthiban Pazhamalai & Vimal Kumar Mariappan & Swapnil Shital Nardekar & Surjit Sahoo & Sang-Jae Kim, 2020. "Probing the energy conversion process in piezoelectric-driven electrochemical self-charging supercapacitor power cell using piezoelectrochemical spectroscopy," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-15808-6
    DOI: 10.1038/s41467-020-15808-6
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    Cited by:

    1. Yuanjie Su & Weixiong Li & Xiaoxing Cheng & Yihao Zhou & Shuai Yang & Xu Zhang & Chunxu Chen & Tiannan Yang & Hong Pan & Guangzhong Xie & Guorui Chen & Xun Zhao & Xiao Xiao & Bei Li & Huiling Tai & Ya, 2022. "High-performance piezoelectric composites via β phase programming," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Padha, Bhavya & Verma, Sonali & Prerna, & Ahmed, Aamir & Patole, Shashikant P. & Arya, Sandeep, 2024. "Plastic turned into MXene–based pyro-piezoelectric hybrid nanogenerator-driven self-powered wearable symmetric supercapacitor," Applied Energy, Elsevier, vol. 356(C).

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