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Rational design of crystalline two-dimensional frameworks with highly complicated topological structures

Author

Listed:
  • Rong-Ran Liang

    (University of Chinese Academy of Sciences, Chinese Academy of Sciences)

  • Shun-Qi Xu

    (University of Chinese Academy of Sciences, Chinese Academy of Sciences)

  • Lei Zhang

    (Peking University)

  • Ru-Han A

    (University of Chinese Academy of Sciences, Chinese Academy of Sciences)

  • Pohua Chen

    (Peking University)

  • Fu-Zhi Cui

    (University of Chinese Academy of Sciences, Chinese Academy of Sciences)

  • Qiao-Yan Qi

    (University of Chinese Academy of Sciences, Chinese Academy of Sciences)

  • Junliang Sun

    (Peking University)

  • Xin Zhao

    (University of Chinese Academy of Sciences, Chinese Academy of Sciences)

Abstract

Constructing two-dimensional (2D) polymers with complex tessellation patterns via synthetic chemistry makes a significant contribution not only to the understanding of the emergence of complex hierarchical systems in living organisms, but also to the fabrication of advanced hierarchical materials. However, to achieve such tasks is a great challenge. In this communication we report a facile and general approach to tessellate 2D covalent organic frameworks (COFs) by three or four geometric shapes/sizes, which affords 2D COFs bearing three or four different kinds of pores and increases structural complexity in tessellations of 2D polymers to a much higher level. The complex tessellation patterns of the COFs are elucidated by powder X-ray diffraction studies, theoretical simulations and high-resolution TEM.

Suggested Citation

  • Rong-Ran Liang & Shun-Qi Xu & Lei Zhang & Ru-Han A & Pohua Chen & Fu-Zhi Cui & Qiao-Yan Qi & Junliang Sun & Xin Zhao, 2019. "Rational design of crystalline two-dimensional frameworks with highly complicated topological structures," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-12596-6
    DOI: 10.1038/s41467-019-12596-6
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    Cited by:

    1. Ningning He & Yingdi Zou & Cheng Chen & Minghao Tan & Yingdan Zhang & Xiaofeng Li & Zhimin Jia & Jie Zhang & Honghan Long & Haiyue Peng & Kaifu Yu & Bo Jiang & Ziqian Han & Ning Liu & Yang Li & Lijian, 2024. "Constructing ordered and tunable extrinsic porosity in covalent organic frameworks via water-mediated soft-template strategy," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Yong Liu & Liangchao Yuan & Wenwen Chi & Wang-Kang Han & Jinfang Zhang & Huan Pang & Zhongchang Wang & Zhi-Guo Gu, 2024. "Cairo pentagon tessellated covalent organic frameworks with mcm topology for near-infrared phototherapy," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Shu-Yan Jiang & Zhi-Bei Zhou & Shi-Xian Gan & Ya Lu & Chao Liu & Qiao-Yan Qi & Jin Yao & Xin Zhao, 2024. "Creating amphiphilic porosity in two-dimensional covalent organic frameworks via steric-hindrance-mediated precision hydrophilic-hydrophobic microphase separation," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    4. Minghao Liu & Shuai Yang & Xiubei Yang & Cheng-Xing Cui & Guojuan Liu & Xuewen Li & Jun He & George Zheng Chen & Qing Xu & Gaofeng Zeng, 2023. "Post-synthetic modification of covalent organic frameworks for CO2 electroreduction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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