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Metal-organic framework crystal-glass composites

Author

Listed:
  • Jingwei Hou

    (University of Cambridge)

  • Christopher W. Ashling

    (University of Cambridge)

  • Sean M. Collins

    (University of Cambridge)

  • Andraž Krajnc

    (National Institute of Chemistry)

  • Chao Zhou

    (University of Cambridge)

  • Louis Longley

    (University of Cambridge)

  • Duncan N. Johnstone

    (University of Cambridge)

  • Philip A. Chater

    (Harwell Science & Innovation Campus)

  • Shichun Li

    (University of Cambridge
    China Academy of Engineering Physics)

  • Marie-Vanessa Coulet

    (Aix-Marseille Univ, CNRS, MADIREL (UMR 7246))

  • Philip L. Llewellyn

    (Aix-Marseille Univ, CNRS, MADIREL (UMR 7246))

  • François-Xavier Coudert

    (PSL University, CNRS, Institut de Recherche de Chimie Paris)

  • David A. Keen

    (ISIS Facility, Rutherford Appleton Laboratory, Harwell Campus)

  • Paul A. Midgley

    (University of Cambridge)

  • Gregor Mali

    (National Institute of Chemistry)

  • Vicki Chen

    (University of New South Wales
    University of Queensland)

  • Thomas D. Bennett

    (University of Cambridge)

Abstract

The majority of research into metal-organic frameworks (MOFs) focuses on their crystalline nature. Recent research has revealed solid-liquid transitions within the family, which we use here to create a class of functional, stable and porous composite materials. Described herein is the design, synthesis, and characterisation of MOF crystal-glass composites, formed by dispersing crystalline MOFs within a MOF-glass matrix. The coordinative bonding and chemical structure of a MIL-53 crystalline phase are preserved within the ZIF-62 glass matrix. Whilst separated phases, the interfacial interactions between the closely contacted microdomains improve the mechanical properties of the composite glass. More significantly, the high temperature open pore phase of MIL-53, which spontaneously transforms to a narrow pore upon cooling in the presence of water, is stabilised at room temperature in the crystal-glass composite. This leads to a significant improvement of CO2 adsorption capacity.

Suggested Citation

  • Jingwei Hou & Christopher W. Ashling & Sean M. Collins & Andraž Krajnc & Chao Zhou & Louis Longley & Duncan N. Johnstone & Philip A. Chater & Shichun Li & Marie-Vanessa Coulet & Philip L. Llewellyn & , 2019. "Metal-organic framework crystal-glass composites," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-10470-z
    DOI: 10.1038/s41467-019-10470-z
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    Cited by:

    1. Minhyuk Kim & Hwa-Sub Lee & Dong-Hyun Seo & Sung June Cho & Eun-chae Jeon & Hoi Ri Moon, 2024. "Melt-quenched carboxylate metal–organic framework glasses," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Zihui Zhang & Yingbo Zhao, 2024. "Transparent and high-porosity aluminum alkoxide network-forming glasses," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    3. Wen-Long Xue & Pascal Kolodzeiski & Hanna Aucharova & Suresh Vasa & Athanasios Koutsianos & Roman Pallach & Jianbo Song & Louis Frentzel-Beyme & Rasmus Linser & Sebastian Henke, 2024. "Highly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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