Author
Listed:
- Mingzhe Chen
(Institute for Superconducting and Electronic Materials, University of Wollongong)
- Weibo Hua
(Institute for Applied Materials-Energy Storage Systems (IAM-ESS), Karlsruhe Institute of Technology (KIT))
- Jin Xiao
(School of Science, Hunan University of Technology
State Key Laboratory of the Superlattices and Microstructures Institute of Semiconductors, Chinese Academy of Sciences)
- David Cortie
(Institute for Superconducting and Electronic Materials, University of Wollongong)
- Weihua Chen
(Zhengzhou University)
- Enhui Wang
(Institute for Superconducting and Electronic Materials, University of Wollongong
Sichuan University)
- Zhe Hu
(Institute for Superconducting and Electronic Materials, University of Wollongong)
- Qinfen Gu
(Australian Synchrotron)
- Xiaolin Wang
(Institute for Superconducting and Electronic Materials, University of Wollongong)
- Sylvio Indris
(Institute for Applied Materials-Energy Storage Systems (IAM-ESS), Karlsruhe Institute of Technology (KIT))
- Shu-Lei Chou
(Institute for Superconducting and Electronic Materials, University of Wollongong)
- Shi-Xue Dou
(Institute for Superconducting and Electronic Materials, University of Wollongong)
Abstract
The development of low-cost and long-lasting all-climate cathode materials for the sodium ion battery has been one of the key issues for the success of large-scale energy storage. One option is the utilization of earth-abundant elements such as iron. Here, we synthesize a NASICON-type tuneable Na4Fe3(PO4)2(P2O7)/C nanocomposite which shows both excellent rate performance and outstanding cycling stability over more than 4400 cycles. Its air stability and all-climate properties are investigated, and its potential as the sodium host in full cells has been studied. A remarkably low volume change of 4.0% is observed. Its high sodium diffusion coefficient has been measured and analysed via first-principles calculations, and its three-dimensional sodium ion diffusion pathways are identified. Our results indicate that this low-cost and environmentally friendly Na4Fe3(PO4)2(P2O7)/C nanocomposite could be a competitive candidate material for sodium ion batteries.
Suggested Citation
Mingzhe Chen & Weibo Hua & Jin Xiao & David Cortie & Weihua Chen & Enhui Wang & Zhe Hu & Qinfen Gu & Xiaolin Wang & Sylvio Indris & Shu-Lei Chou & Shi-Xue Dou, 2019.
"NASICON-type air-stable and all-climate cathode for sodium-ion batteries with low cost and high-power density,"
Nature Communications, Nature, vol. 10(1), pages 1-11, December.
Handle:
RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-09170-5
DOI: 10.1038/s41467-019-09170-5
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Cited by:
- Wenyi Liu & Wenjun Cui & Chengjun Yi & Jiale Xia & Jinbing Shang & Weifei Hu & Zhuo Wang & Xiahan Sang & Yuanyuan Li & Jinping Liu, 2024.
"Understanding pillar chemistry in potassium-containing polyanion materials for long-lasting sodium-ion batteries,"
Nature Communications, Nature, vol. 15(1), pages 1-15, December.
- Du, Peng & Cao, Liang & Zhang, Bao & Wang, Chunhui & Xiao, Zhiming & Zhang, Jiafeng & Wang, Dong & Ou, Xing, 2021.
"Recent progress on heterostructure materials for next-generation sodium/potassium ion batteries,"
Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
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