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Clear and transparent nanocrystals for infrared-responsive carrier transfer

Author

Listed:
  • Masanori Sakamoto

    (Kyoto University, Gokasho)

  • Tokuhisa Kawawaki

    (Kyoto University, Gokasho)

  • Masato Kimura

    (Kyoto University, Gokasho)

  • Taizo Yoshinaga

    (University of Tsukuba)

  • Junie Jhon M. Vequizo

    (Graduate School of Engineering, Toyota Technological Institute)

  • Hironori Matsunaga

    (Graduate School of Engineering, Toyota Technological Institute)

  • Chandana Sampath Kumara Ranasinghe

    (Graduate School of Engineering, Toyota Technological Institute)

  • Akira Yamakata

    (Graduate School of Engineering, Toyota Technological Institute)

  • Hiroyuki Matsuzaki

    (National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 2)

  • Akihiro Furube

    (Tokushima University)

  • Toshiharu Teranishi

    (Kyoto University, Gokasho)

Abstract

Infrared-light-induced carrier transfer is a key technology for ‘invisible’ optical devices for information communication systems and energy devices. However, clear and colourless photo-induced carrier transfer has not yet been demonstrated in the field of photochemistry, to the best of our knowledge. Here, we resolve this problem by employing short-wavelength-infrared (1400–4000 nm) localized surface plasmon resonance-induced electron injection from indium tin oxide nanocrystals to transparent metal oxides. The time-resolved infrared measurements visualize the dynamics of the carrier in this invisible system. Selective excitation of localized surface plasmon resonances causes hot electron injection with high efficiency (33%) and long-lived charge separation (~ 2–200 μs). We anticipate our study not only provides a breakthrough for plasmonic carrier transfer systems but may also stimulate the invention of state-of-the-art invisible optical devices.

Suggested Citation

  • Masanori Sakamoto & Tokuhisa Kawawaki & Masato Kimura & Taizo Yoshinaga & Junie Jhon M. Vequizo & Hironori Matsunaga & Chandana Sampath Kumara Ranasinghe & Akira Yamakata & Hiroyuki Matsuzaki & Akihir, 2019. "Clear and transparent nanocrystals for infrared-responsive carrier transfer," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
  • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-018-08226-2
    DOI: 10.1038/s41467-018-08226-2
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    Cited by:

    1. Masanori Sakamoto & Masaki Hada & Wataru Ota & Fumihiko Uesugi & Tohru Sato, 2023. "Localised surface plasmon resonance inducing cooperative Jahn–Teller effect for crystal phase-change in a nanocrystal," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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