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Sulfide resorption during crustal ascent and degassing of oceanic plateau basalts

Author

Listed:
  • C. D. J. Reekie

    (University of Cambridge)

  • F. E. Jenner

    (The Open University)

  • D. J. Smythe

    (University of Oxford)

  • E. H. Hauri

    (Carnegie Institution of Washington)

  • E. S. Bullock

    (Carnegie Institution of Washington)

  • H. M. Williams

    (University of Cambridge)

Abstract

Mantle plume-related magmas typically have higher chalcophile and siderophile element (CSE) contents than mid-ocean ridge basalts (MORB). These differences are often attributed to sulfide-under-saturation of plume-related melts. However, because of eruption-related degassing of sulfur (S) and the compositional, pressure, temperature and redox effects on S-solubility, understanding the magmatic behavior of S is challenging. Using CSE data for oceanic plateau basalts (OPB), which rarely degas S, we show that many OPB are sulfide-saturated. Differences in the timing of sulfide-saturation between individual OPB suites can be explained by pressure effects on sulfur solubility associated with ascent through over-thickened crust. Importantly, where S-degassing does occur, OPB have higher CSE contents than S-undegassed melts at similar stages of differentiation. This can be explained by resorption of earlier-formed sulfides, which might play an important role in enriching degassed melts in sulfide-compatible CSE and potentially contributes to anomalous enrichments of CSE in the crust.

Suggested Citation

  • C. D. J. Reekie & F. E. Jenner & D. J. Smythe & E. H. Hauri & E. S. Bullock & H. M. Williams, 2019. "Sulfide resorption during crustal ascent and degassing of oceanic plateau basalts," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-018-08001-3
    DOI: 10.1038/s41467-018-08001-3
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