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Lithium intercalation into bilayer graphene

Author

Listed:
  • Kemeng Ji

    (Tohoku University
    Tohoku University)

  • Jiuhui Han

    (Tohoku University
    Tohoku University)

  • Akihiko Hirata

    (Tohoku University)

  • Takeshi Fujita

    (Tohoku University)

  • Yuhao Shen

    (Tohoku University
    East China Normal University)

  • Shoucong Ning

    (Hong Kong University of Science and Technology)

  • Pan Liu

    (Tohoku University)

  • Hamzeh Kashani

    (Tohoku University
    Tohoku University)

  • Yuan Tian

    (Tohoku University
    Tohoku University)

  • Yoshikazu Ito

    (University of Tsukuba
    PRESTO, Japan Science and Technology Agency)

  • Jun-ichi Fujita

    (University of Tsukuba)

  • Yutaka Oyama

    (Tohoku University)

Abstract

The real capacity of graphene and the lithium-storage process in graphite are two currently perplexing problems in the field of lithium ion batteries. Here we demonstrate a three-dimensional bilayer graphene foam with few defects and a predominant Bernal stacking configuration, and systematically investigate its lithium-storage capacity, process, kinetics, and resistances. We clarify that lithium atoms can be stored only in the graphene interlayer and propose the first ever planar lithium-intercalation model for graphenic carbons. Corroborated by theoretical calculations, various physiochemical characterizations of the staged lithium bilayer graphene products further reveal the regular lithium-intercalation phenomena and thus fully illustrate this elementary lithium storage pattern of two-dimension. These findings not only make the commercial graphite the first electrode with clear lithium-storage process, but also guide the development of graphene materials in lithium ion batteries.

Suggested Citation

  • Kemeng Ji & Jiuhui Han & Akihiko Hirata & Takeshi Fujita & Yuhao Shen & Shoucong Ning & Pan Liu & Hamzeh Kashani & Yuan Tian & Yoshikazu Ito & Jun-ichi Fujita & Yutaka Oyama, 2019. "Lithium intercalation into bilayer graphene," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-018-07942-z
    DOI: 10.1038/s41467-018-07942-z
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    Cited by:

    1. Pandey, Mayank & Deshmukh, Kalim & Raman, Akhila & Asok, Aparna & Appukuttan, Saritha & Suman, G.R., 2024. "Prospects of MXene and graphene for energy storage and conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    2. Miao Bai & Xiaoyu Tang & Min Zhang & Helin Wang & Zhiqiao Wang & Ahu Shao & Yue Ma, 2024. "An in-situ polymerization strategy for gel polymer electrolyte Si||Ni-rich lithium-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Thomas Astles & James G. McHugh & Rui Zhang & Qian Guo & Madeleine Howe & Zefei Wu & Kornelia Indykiewicz & Alex Summerfield & Zachary A. H. Goodwin & Sergey Slizovskiy & Daniil Domaretskiy & Andre K., 2024. "In-plane staging in lithium-ion intercalation of bilayer graphene," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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