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Sustainability Evaluation of the Al-Qasab Playa by Integrating Hydrogeochemical and Graphical, ArcGIS Watershed, and Thermodynamic Geochemical Modeling Approaches

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  • Hassan E. Gomaa

    (Department of Chemistry, College of Science and Humanities, Shaqra University, Ad-Dawadmi 11911, Saudi Arabia
    Department of Nuclear Safety Engineering, Nuclear Installations Safety Division, Atomic Energy Authority, Cairo 11765, Egypt
    Water Research Group, College of Science and Humanities at Ad-Dawadmi, Shaqra University, Ad-Dawadmi 11911, Saudi Arabia)

  • Fatma A. Gomaa

    (Department of Chemistry, College of Science and Humanities, Shaqra University, Ad-Dawadmi 11911, Saudi Arabia
    Department of Chemistry, College of Women for Science, Arts, and Education, Ain Shams University, Cairo 11757, Egypt)

  • Sami M. Abdel Azeem

    (Water Research Group, College of Science and Humanities at Ad-Dawadmi, Shaqra University, Ad-Dawadmi 11911, Saudi Arabia
    Chemistry Department, College of Science and Humanities, Shaqra University, Al-Quwayiyah 11971, Saudi Arabia
    Chemistry Department, Faculty of Science, Fayoum University, Fayoum 63514, Egypt)

  • Abdullah A. Alotaibi

    (Department of Chemistry, College of Science and Humanities, Shaqra University, Ad-Dawadmi 11911, Saudi Arabia
    Water Research Group, College of Science and Humanities at Ad-Dawadmi, Shaqra University, Ad-Dawadmi 11911, Saudi Arabia)

Abstract

Drawing development plans requires evaluating the available resources and assessing their sustainable and subsequent utilization-driven environmental impacts. The current work is concerned with evaluating the sustainability of the halite harvesting process from Al-Qasab Playa, Shaqra, Central Saudi Arabia. The authors integrated, conceptually and quantitatively, ArcGIS-processed SRTM-DEM (Shuttle Radar Topography Mission-Digital Elevation Model) data, hydrogeochemical and thermodynamic-based geochemical modelling, and graphical approaches to achieve the ultimate aims of the study. The watershed is identified as a nonmarine closed basin with a drainage area of 1290 km 2 , with the slope controlling recharge to the Playa. The Chadha plot including the rainwater exhibits linear regression, with an R 2 value of 0.9947, confirming the rainwater origin of the Playa water. The hardness-forming ions are primarily removed in pond 3, eliminating the need for costly and power-consuming steps of softening with ion exchange resins or nanofiltration as it can be used directly as a readily available feed for the chlor-alkali process for producing NaOH, Cl 2 , and H 2 gases through electrolysis. XRD (X-ray diffraction) analysis and the SEM-EDS (Scanning electron microscopy-energy dispersive X-ray spectroscopy) of the harvested halite confirmed its purity. An improved design of the current folkloric harvesting process has been proposed based on the saturation indices calculated thermodynamically to provide a readily available feed intake for the electrolysis chlor-alkali process with or without minimal pretreatment to produce higher value chemicals. The methodological aspects presented here are deemed robust and valid for applications in other study areas, including the assessment of the exploitation of the rejected brine from the desalination plants to achieve the zero liquid discharge approach, as well as other types of sabkhas, regardless of their geographical location.

Suggested Citation

  • Hassan E. Gomaa & Fatma A. Gomaa & Sami M. Abdel Azeem & Abdullah A. Alotaibi, 2024. "Sustainability Evaluation of the Al-Qasab Playa by Integrating Hydrogeochemical and Graphical, ArcGIS Watershed, and Thermodynamic Geochemical Modeling Approaches," Sustainability, MDPI, vol. 16(5), pages 1-26, March.
  • Handle: RePEc:gam:jsusta:v:16:y:2024:i:5:p:2118-:d:1350924
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    References listed on IDEAS

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    1. Bouwer, Herman, 1994. "Irrigation and global water outlook," Agricultural Water Management, Elsevier, vol. 25(3), pages 221-231, July.
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