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Evaluation of Ca-Based Sorbents for Gaseous HCl Emissions Adsorption

Author

Listed:
  • Marco Ravina

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

  • Edoardo Marotta

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

  • Alberto Cerutti

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

  • Giovanna Zanetti

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

  • Barbara Ruffino

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

  • Deborah Panepinto

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

  • Mariachiara Zanetti

    (Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy)

Abstract

The problem of acid gas exhaust emissions treatment has not been fully resolved at present. Dry adsorption of acid gases with alkaline sorbents is currently being investigated, to improve solid sorbents. In this study, 5 types of hydrated lime were characterised and tested. The sorption capacities were measured by means of a system consisting of a feed line (HCl/N 2 ), a thermostatic reactor and a water absorber. The physical characteristics of sorbent samples were also compared. Analyses conducted with scanning electronic microscopy revealed that sample C1 showed uniform particle distribution. Samples C2 and C3 showed the co-presence of fine and coarse particles. Sample C4 showed very fine particles with agglomeration phenomena. In sample C5, fibrous elements were found. Energy dispersive spectrometry (EDS) analyses showed a similar composition of the samples, with the exception of the presence of Mg in some of them. After 30 min of testing, the following differences in sorption capacities with respect to C1 (3.59 mg g −1 ) were found: C2, −20%; C3, −13%; C4, −17%; C5, −3%. Higher sorption capacities were associated with more uniform particle size distributions. Conversely, agglomeration of fine particles may have adversely affected the performance of sorbents.

Suggested Citation

  • Marco Ravina & Edoardo Marotta & Alberto Cerutti & Giovanna Zanetti & Barbara Ruffino & Deborah Panepinto & Mariachiara Zanetti, 2023. "Evaluation of Ca-Based Sorbents for Gaseous HCl Emissions Adsorption," Sustainability, MDPI, vol. 15(14), pages 1-16, July.
  • Handle: RePEc:gam:jsusta:v:15:y:2023:i:14:p:10882-:d:1191683
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    Cited by:

    1. Marco Schiavon & Marco Ravina & Mariachiara Zanetti & Deborah Panepinto, 2024. "State-of-the-Art and Recent Advances in the Abatement of Gaseous Pollutants from Waste-to-Energy," Energies, MDPI, vol. 17(3), pages 1-23, January.

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