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Development and Optimization of Geopolymers Made with Desert Dune Sand and Blast Furnace Slag

Author

Listed:
  • Abdulkader El-Mir

    (Department of Civil and Environmental Engineering, UAE University, Al Ain P.O. Box 15551, United Arab Emirates)

  • Hilal El-Hassan

    (Department of Civil and Environmental Engineering, UAE University, Al Ain P.O. Box 15551, United Arab Emirates)

  • Amr El-Dieb

    (Department of Civil and Environmental Engineering, UAE University, Al Ain P.O. Box 15551, United Arab Emirates)

  • Abdelrahman Alsallamin

    (Department of Civil and Environmental Engineering, UAE University, Al Ain P.O. Box 15551, United Arab Emirates)

Abstract

This study assesses the effect of mix design parameters on the fresh and hardened properties, cost, and carbon footprint of geopolymer mortar made with desert dune fines (DDF) and blast furnace slag (BFS). Taguchi method was employed in designing the experiments. Four factors were considered, each having three levels, leading to a total of nine geopolymer mortar mixes. The factors comprised the DDF replacement percentage, alkali-activator solution to binder ratio (AAS/B), sodium silicate-to-sodium hydroxide ratio (SS/SH), and sodium hydroxide (SH) molarity. Ten performance criteria were evaluated, including the flowability, final setting time, hardened density, 1, 7, and 28-day compressive strengths, water absorption, sorptivity, cost, and carbon footprint. ANOVA was carried out to estimate the contribution of each factor towards the response criteria. Further, TOPSIS analysis was utilized to optimize the mixture proportions of DDF-BFS blended geopolymer mortar. Experimental results showed that up to 25% DDF replacement enhanced the density, strength, and durability of the geopolymers with minor impact on the flowability and setting time. Higher replacement percentages had a detrimental impact on the performance but could still be utilized in specific mortar construction applications. The other factors had more limited contributions to the performance, evidenced by the ANOVA. TOPSIS method revealed the optimum mix to be made with DDF replacement of 25%, AAS/B of 0.5, SS/SH of 1.5, and SH molarity of 10 M. Different multivariable regression models were also developed to predict the fresh and hardened properties of the DDF-BFS geopolymer mortars using the mix design parameters.

Suggested Citation

  • Abdulkader El-Mir & Hilal El-Hassan & Amr El-Dieb & Abdelrahman Alsallamin, 2022. "Development and Optimization of Geopolymers Made with Desert Dune Sand and Blast Furnace Slag," Sustainability, MDPI, vol. 14(13), pages 1-21, June.
  • Handle: RePEc:gam:jsusta:v:14:y:2022:i:13:p:7845-:d:849181
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    References listed on IDEAS

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    1. Hilal El-Hassan & Jamal Medljy & Tamer El-Maaddawy, 2021. "Properties of Steel Fiber-Reinforced Alkali-Activated Slag Concrete Made with Recycled Concrete Aggregates and Dune Sand," Sustainability, MDPI, vol. 13(14), pages 1-24, July.
    2. Mohammed H. Alzard & Hilal El-Hassan & Tamer El-Maaddawy, 2021. "Environmental and Economic Life Cycle Assessment of Recycled Aggregates Concrete in the United Arab Emirates," Sustainability, MDPI, vol. 13(18), pages 1-26, September.
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    Cited by:

    1. Faiz Habib Anwar & Hilal El-Hassan & Mohamed Hamouda & Abdulkader El-Mir & Safa Mohammed & Kim Hung Mo, 2022. "Optimization of Pervious Geopolymer Concrete Using TOPSIS-Based Taguchi Method," Sustainability, MDPI, vol. 14(14), pages 1-20, July.

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