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Effects of Silicic Acid on Leaching Behavior of Arsenic from Spent Calcium-Based Adsorbents with Arsenite

Author

Listed:
  • Hajime Sugita

    (Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba 305-8567, Japan)

  • Terumi Oguma

    (Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba 305-8567, Japan)

  • Junko Hara

    (Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba 305-8567, Japan)

  • Ming Zhang

    (Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba 305-8567, Japan)

  • Yoshishige Kawabe

    (Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba 305-8567, Japan)

Abstract

The spent adsorbents that remain after being used to purify As-contaminated water constitute waste containing a large amount of As. These spent adsorbents, after being disposed, are likely to come into contact with silicic acid leached from the soil or cementitious solidification materials. Thus, it is crucial the evaluate the effects of silicic acid on spent adsorbents. In this study, the effects of silicic acid on spent Ca-based (CaO and Ca(OH) 2 ) adsorbents with arsenite were investigated. The As leaching ratio for the spent adsorbents decreased with an increase in the initial concentration of silicic acid in the liquid. Under the tested conditions, the As leaching ratio decreased from 8–9% to less than 0.7% in the presence of silicic acid at an initial Si-normalized concentration of 100 mg/L. The primary mechanism behind the inhibition of As leaching by silicic acid was determined to be re-immobilization via the incorporation of arsenite during the formation of calcium silicates. In the presence of silicic acid, spent Ca-based adsorbents with arsenite had a lower As leaching ratio than those with arsenate. Therefore, spent Ca-based adsorbents with arsenite were found to have a higher environmental stability than those with arsenate.

Suggested Citation

  • Hajime Sugita & Terumi Oguma & Junko Hara & Ming Zhang & Yoshishige Kawabe, 2021. "Effects of Silicic Acid on Leaching Behavior of Arsenic from Spent Calcium-Based Adsorbents with Arsenite," Sustainability, MDPI, vol. 13(23), pages 1-18, November.
    • Handle: RePEc:gam:jsusta:v:13:y:2021:i:23:p:12937-:d:685608
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    References listed on IDEAS

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    1. Senanayake, Nari & Mukherji, Aditi, 2014. "Irrigating with arsenic contaminated groundwater in West Bengal and Bangladesh: A review of interventions for mitigating adverse health and crop outcomes," Agricultural Water Management, Elsevier, vol. 135(C), pages 90-99.
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    Cited by:

    1. Hajime Sugita & Terumi Oguma & Junko Hara & Ming Zhang & Yoshishige Kawabe, 2022. "Effects of Silicic Acid on Leaching Behavior of Arsenic from Spent Magnesium-Based Adsorbents Containing Arsenite," Sustainability, MDPI, vol. 14(7), pages 1-19, April.
    2. Hajime Sugita & Kazuya Morimoto & Takeshi Saito & Junko Hara, 2024. "Effects of Soils on Environmental Stability of Spent Mg-Based and Ca-Based Adsorbents Containing Arsenite," Sustainability, MDPI, vol. 16(10), pages 1-18, May.

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    1. Hajime Sugita & Kazuya Morimoto & Takeshi Saito & Junko Hara, 2024. "Effects of Soils on Environmental Stability of Spent Mg-Based and Ca-Based Adsorbents Containing Arsenite," Sustainability, MDPI, vol. 16(10), pages 1-18, May.
    2. Hajime Sugita & Terumi Oguma & Junko Hara & Ming Zhang & Yoshishige Kawabe, 2023. "Removal of Arsenate from Contaminated Water via Combined Addition of Magnesium-Based and Calcium-Based Adsorbents," Sustainability, MDPI, vol. 15(5), pages 1-22, March.

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