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Distribution and Potential Availability of As, Metals and P in Sediments from a Riverine Reservoir in a Rural Mountainous Catchment (NE Portugal)

Author

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  • Anabela R. Reis

    (Department of Geology, School of Life and Environmental Sciences, University of Trás-os-Montes e Alto Douro (UTAD), 5000-801 Vila Real, Portugal
    Geosciences Centre, University of Coimbra (Polo II), 3030-790 Coimbra, Portugal)

  • Marta Roboredo

    (Chemistry Center Vila Real, Department of Biology and Environment, School of Life and Environmental Sciences, University of Trás-os-Montes e Alto Douro (UTAD), 5000-801 Vila Real, Portugal)

  • João P. R. M. Pinto

    (Amber Energy, Cardiff CF10 1FS, UK)

  • Bernardete Vieira

    (School of Agrarian and Veterinary Sciences, University of Trás-os-Montes e Alto Douro (UTAD), 5000-801 Vila Real, Portugal)

  • Simone G. P. Varandas

    (Centre for Research and Technology of Agro-Environment and Biological Sciences, Department of Forestry and CITAB/UTAD, University of Trás-os-Montes and Alto Douro (UTAD), 5000-801 Vila Real, Portugal)

  • Luis F. S. Fernandes

    (Centre for Research and Technology of Agro-Environment and Biological Sciences, Department of Engineering and CITAB/UTAD, University of Trás-os-Montes and Alto Douro (UTAD), 5000-801 Vila Real, Portugal)

  • Fernando A. L. Pacheco

    (Chemistry Center Vila Real, Department of Geology, University of Trás-os-Montes e Alto Douro (UTAD), 5000-801 Vila Real, Portugal)

Abstract

A geochemical investigation was carried out on the bottom sediments of a riverine reservoir, located in a mountainous rural region (NE Portugal), with the aim of evaluating the contents of As, metals and P and their potential availability. The elements contents were detected in the following ranges (µg g −1 ): As (18–64); Cr (32–128); Cu (39–93); Ni (18–80); Pb (49–160); Zn (207–334); P (1705–2681). The reducible fraction is the most significant in the retention of the elements. Based on their potential relative mobility, the detected metals could be classed as follows: Zn > As, Pb > Cu > Cr, Ni. The results on geochemical partitioning were revealed to be important when the Sediment Quality Guidelines (SQGs) were considered. Arsenic, Cr, Ni, Pb and Zn showed total contents exceeding the values of Probable Effect Level (PEL), but only As occurred in the most potentially available form; Cr and Ni can be considered relatively unavailable, since these are mainly associated with the residual phase. Locally, oxygen depletion could release P into the water column due to the higher concentrations in Fe-P and CDB-P fractions. The potential availability of As, metals and P in sediments indicates that the quality of sediments accumulated in small reservoirs should be considered in management policies.

Suggested Citation

  • Anabela R. Reis & Marta Roboredo & João P. R. M. Pinto & Bernardete Vieira & Simone G. P. Varandas & Luis F. S. Fernandes & Fernando A. L. Pacheco, 2021. "Distribution and Potential Availability of As, Metals and P in Sediments from a Riverine Reservoir in a Rural Mountainous Catchment (NE Portugal)," IJERPH, MDPI, vol. 18(11), pages 1-15, May.
  • Handle: RePEc:gam:jijerp:v:18:y:2021:i:11:p:5616-:d:561338
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    References listed on IDEAS

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    1. Xiaojun Yan & Wenhao Yang & Xiaohui Chen & Mingkuang Wang & Weiqi Wang & Delian Ye & Liangquan Wu, 2020. "Soil Phosphorus Pools, Bioavailability and Environmental Risk in Response to the Phosphorus Supply in the Red Soil of Southern China," IJERPH, MDPI, vol. 17(20), pages 1-16, October.
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    Cited by:

    1. Martyna A. Rzetala & Robert Machowski & Maksymilian Solarski & Daniel Bakota & Arkadiusz Płomiński & Mariusz Rzetala, 2023. "Toxic Metals, Non-Metals and Metalloids in Bottom Sediments as a Geoecological Indicator of a Water Body’s Suitability for Recreational Use," IJERPH, MDPI, vol. 20(5), pages 1-23, February.

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