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Identification and Estimation of Solute Storage and Release in Karst Water Systems, South China

Author

Listed:
  • Liang Zhang

    (School of Environmental Studies, China University of Geosciences, Wuhan 430074, China)

  • Mingming Luo

    (School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
    Key Laboratory of Karst Dynamics, MNR/GZAR, Institute of Karst Geology, Chinese Academy of Geological Sciences, Guilin 541004, China)

  • Zhihua Chen

    (School of Environmental Studies, China University of Geosciences, Wuhan 430074, China)

Abstract

Solute storage and release in groundwater are key processes in solute transport for groundwater remediation and protection. In karst areas where concentrated recharge conditions exist, pollution incidents can easily occur in springs that are hydraulically connected to densely inhabited karst depressions. The intrinsic heterogeneity common in karst media makes modeling solute transport very difficult with great uncertainty. Meanwhile, it is noteworthy that solute storage and release within subsurface conduits and fissures exhibit strong controlling function on pollutant attenuation during underground floods. Consequently, in this paper, we identified and estimated the solute storage and release processes in karst water systems under concentrated recharge conditions. The methodology uses the advection–dispersion method and field tracer tests to characterize solute transport in different flow paths. Two solute transport pathways were established (i.e., linear pathway (direct transport through karst conduits) and dynamic pathway (flow through fissures)). Advection–dispersion equations were used to fit the breakthrough curves in conduit flow, while the volume of solute storage in fissures were calculated by segmenting the best fitting curves from the total breakthrough curves. The results show that, greater recharge flow or stronger dynamic conditions leads to lower solute storage rate, with the storage rate values less than 10% at high water level conditions. In addition, longer residence time was recorded for solute exchange between conduits and fissures at the low water level condition, thereby contributing to a higher solute storage rate of 26% in the dynamic pathway.

Suggested Citation

  • Liang Zhang & Mingming Luo & Zhihua Chen, 2020. "Identification and Estimation of Solute Storage and Release in Karst Water Systems, South China," IJERPH, MDPI, vol. 17(19), pages 1-13, October.
  • Handle: RePEc:gam:jijerp:v:17:y:2020:i:19:p:7219-:d:423048
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    References listed on IDEAS

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    1. Hugo Henrique Cardoso de Salis & Adriana Monteiro da Costa & João Herbert Moreira Vianna & Marysol Azeneth Schuler & Annika Künne & Luís Filipe Sanches Fernandes & Fernando António Leal Pacheco, 2019. "Hydrologic Modeling for Sustainable Water Resources Management in Urbanized Karst Areas," IJERPH, MDPI, vol. 16(14), pages 1-19, July.
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    Cited by:

    1. Wei Chang & Junwei Wan & Jiahua Tan & Zongxing Wang & Cong Jiang & Kun Huang, 2021. "Responses of Spring Discharge to Different Rainfall Events for Single-Conduit Karst Aquifers in Western Hunan Province, China," IJERPH, MDPI, vol. 18(11), pages 1-17, May.

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