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Preparation and Doping Mode of Doped LiMn 2 O 4 for Li-Ion Batteries

Author

Listed:
  • Qiuling Liu

    (Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

  • Shengping Wang

    (Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

  • Haibo Tan

    (Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

  • Zhigao Yang

    (Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

  • Jian Zeng

    (Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

Abstract

Spinel LiMn 2 O 4 is an appealing candidate cathode material for Li-ion rechargeable batteries, but it suffers from severe capacity fading, especially at higher temperature (55 °C) during discharging/charging. In recent years, many attempts have been made to synthesize modified LiMn 2 O 4 . This paper reviews the recent research on the preparation and doping modes of doped LiMn 2 O 4 for modifying the LiMn 2 O 4 . We firstly compared preparation methods for doped spinel LiMn 2 O 4 , such as solid state reactions and solution synthetic methods. Then we mainly discuss doping modes reported in recent years, such as bulk doping, surface doping and combined doping. A comparison of different doping modes is also provided. The research shows that the multiple-ion doping and combined doping modes of LiMn 2 O 4 used in Li-ion battery are excellent for improving different aspects of the electrochemical performance which holds great promise in the future. From this paper, we also can see that spinel LiMnO 4 as an attractive candidate cathode material for Li-ion batteries.

Suggested Citation

  • Qiuling Liu & Shengping Wang & Haibo Tan & Zhigao Yang & Jian Zeng, 2013. "Preparation and Doping Mode of Doped LiMn 2 O 4 for Li-Ion Batteries," Energies, MDPI, vol. 6(3), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:6:y:2013:i:3:p:1718-1730:d:24200
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    Cited by:

    1. Ngoc Hung Vu & Van-Duong Dao & Ha Tran Huu & Won Bin Im, 2020. "Effect of Synthesis Temperature on Structure and Electrochemical Performance of Spinel-Layered Li 1.33 MnTiO 4 +z in Li-Ion Batteries," Energies, MDPI, vol. 13(11), pages 1-11, June.

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