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Direct Hydrothermal Synthesis and Characterization of Zr–Ce-Incorporated SBA-15 Catalysts for the Pyrolysis Reaction of Algal Biomass

Author

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  • Simona-Bianca Ghimiș

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

  • Florin Oancea

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

  • Monica-Florentina Raduly

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

  • Andreea-Luiza Mîrț

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

  • Bogdan Trică

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

  • Mihaela Cîlțea-Udrescu

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

  • Gabriel Vasilievici

    (National Institute for Research & Development in Chemistry and Petrochemistry-ICECHIM Bucharest, 202 Spl. Independentei, 6th District, 060021 Bucharest, Romania)

Abstract

In recent years, algae have emerged as a promising feedstock for biofuel production, due to their eco-friendly, sustainable, and renewable nature. Various methods, including chemical, biochemical, and thermochemical processes, are used to convert algal biomass into biofuels. Pyrolysis, a widely recognized thermochemical technique, involves high temperature and pressure to generate biochar and bio-oil from diverse algal sources. Various pyrolytic processes transform algal biomass into biochar and bio-oil, including low pyrolysis, fast pyrolysis, catalytic pyrolysis, microwave-assisted pyrolysis, and hydropyrolysis. These methods are utilized to convert a range of microalgae and cyanobacteria into biochar and bio-oil. In this publication, we will discuss catalytic pyrolysis using mesoporous materials, such as SBA-15. Mesoporous catalysts have earned significant attention for catalytic reactions, due to their high surface area, facilitating the better distribution of impregnated metal. Pyrolysis conducted in the presence of a mesoporous catalyst is viewed more as efficient, compared to reactions occurring within the smaller microporous cavities of traditional zeolites. SBA-15 supports with incorporated Zr and/or Ce were synthesized using the direct hydrothermal synthesis method. The catalyst was characterized using structural and morphological technical analysis and utilized for the pyrolysis reaction of the algal biomass.

Suggested Citation

  • Simona-Bianca Ghimiș & Florin Oancea & Monica-Florentina Raduly & Andreea-Luiza Mîrț & Bogdan Trică & Mihaela Cîlțea-Udrescu & Gabriel Vasilievici, 2024. "Direct Hydrothermal Synthesis and Characterization of Zr–Ce-Incorporated SBA-15 Catalysts for the Pyrolysis Reaction of Algal Biomass," Energies, MDPI, vol. 17(15), pages 1-15, July.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:15:p:3765-:d:1446422
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