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GaAs/Si Tandem Solar Cells with an Optically Transparent InAlAs/GaAs Strained Layer Superlattices Dislocation Filter Layer

Author

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  • Yeonhwa Kim

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
    Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea
    These authors contributed equally to this work.)

  • May Angelu Madarang

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
    Division of Nanoscience and Technology, KIST School at University of Science and Technology, Seoul 02792, Republic of Korea
    These authors contributed equally to this work.)

  • Eunkyo Ju

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
    These authors contributed equally to this work.)

  • Tsimafei Laryn

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea)

  • Rafael Jumar Chu

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
    Division of Nanoscience and Technology, KIST School at University of Science and Technology, Seoul 02792, Republic of Korea)

  • Tae Soo Kim

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
    School of Electrical and Electronic Engineering, Yonsei University, Seoul 03722, Republic of Korea)

  • Dae-Hwan Ahn

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea)

  • Taehee Kim

    (Advanced Photovoltaics Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea)

  • In-Hwan Lee

    (Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea)

  • Won Jun Choi

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea)

  • Daehwan Jung

    (Center for Opto-electronic Materials and Devices, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
    Division of Nanoscience and Technology, KIST School at University of Science and Technology, Seoul 02792, Republic of Korea)

Abstract

Epitaxial growth of III–V materials on Si is a promising approach for large-scale, relatively low-cost, and high-efficiency Si-based multi-junction solar cells. Several micron-thick III–V compositionally graded buffers are typically grown to reduce the high threading dislocation density that arises due to the lattice mismatch between III–V and Si. Here, we show that optically transparent n-In 0.1 Al 0.9 As/n-GaAs strained layer superlattice dislocation filter layers can be used to reduce the threading dislocation density in the GaAs buffer on Si while maintaining the GaAs buffer thickness below 2 μm. Electron channeling contrast imaging measurements on the 2 μm n-GaAs/Si template revealed a threading dislocation density of 6 × 10 7 cm −2 owing to the effective n-In 0.1 Al 0.9 As/n-GaAs superlattice filter layers. Our GaAs/Si tandem cell showed an open-circuit voltage of 1.28 V, Si bottom cell limited short-circuit current of 7.2 mA/cm 2 , and an efficiency of 7.5%. This result paves the way toward monolithically integrated triple-junction solar cells on Si substrates.

Suggested Citation

  • Yeonhwa Kim & May Angelu Madarang & Eunkyo Ju & Tsimafei Laryn & Rafael Jumar Chu & Tae Soo Kim & Dae-Hwan Ahn & Taehee Kim & In-Hwan Lee & Won Jun Choi & Daehwan Jung, 2023. "GaAs/Si Tandem Solar Cells with an Optically Transparent InAlAs/GaAs Strained Layer Superlattices Dislocation Filter Layer," Energies, MDPI, vol. 16(3), pages 1-9, January.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:3:p:1158-:d:1042552
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