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Evaluation of Bi-Functional Electrochemical Catalytic Activity of Co 3 O 4 -CoFe 2 O 4 Composite Spinel Oxide

Author

Listed:
  • Ji-Woo Park

    (Department of Chemical Engineering, College of Engineering, Wonkwang University, Iksan 54538, Jeonbuk, Republic of Korea)

  • Young-Wan Ju

    (Department of Chemical Engineering, College of Engineering, Wonkwang University, Iksan 54538, Jeonbuk, Republic of Korea
    ICT Fusion Green Energy Research Institute, Wonkwang University, Iksan 54538, Jeonbuk, Republic of Korea)

Abstract

Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are important for developing energy systems such as fuel cells and metal–air batteries. Precious metal catalysts, such as Pt and IrO 2 , have been considered electrochemical catalysts because of their excellent activity for the ORR and OER. However, their disadvantages, such as low durability for long-term operation and high price, necessitate the development of alternative electrochemical catalysts. Transition metal oxides with excellent electrical conductivity, high efficiency, and stability have been considered alternative electrochemical catalysts owing to their ORR and OER activities, which are similar to those of precious metal catalysts. Therefore, in this study, composite catalyst materials comprising Co 3 O 4 and CoFe 2 O 4 spinel oxides were synthesized via hydrothermal synthesis. The synthesized composite oxides exhibit bi-functional electrochemical catalytic activity for ORR and OER owing to the large active surface area and increased number of oxygen vacancies via the nanostrain in Co 3 O 4 nanoparticles.

Suggested Citation

  • Ji-Woo Park & Young-Wan Ju, 2022. "Evaluation of Bi-Functional Electrochemical Catalytic Activity of Co 3 O 4 -CoFe 2 O 4 Composite Spinel Oxide," Energies, MDPI, vol. 16(1), pages 1-12, December.
  • Handle: RePEc:gam:jeners:v:16:y:2022:i:1:p:173-:d:1013362
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    References listed on IDEAS

    as
    1. Hyo-Young Kim & Young-Wan Ju, 2020. "Fabrication of Mn-N-C Catalyst for Oxygen Reduction Reactions Using Mn-Embedded Carbon Nanofiber," Energies, MDPI, vol. 13(10), pages 1-11, May.
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