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Metal Modified NaY Zeolite as Sorbent for the Ultra-Deep Removal of Thiophene in Simulated Coke Oven Gas

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  • Fanjing Wei

    (State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
    Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China)

  • Xiaoqin Guo

    (State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
    Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China)

  • Weiren Bao

    (State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
    Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China)

  • Liping Chang

    (State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
    Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China)

  • Junjie Liao

    (State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
    Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China)

Abstract

The ultra-deep removal of thiophene is essential for the conversion of coke oven gas to methane and metal modified Y zeolite has excellent thiophene adsorption capacity. The effects of temperature on chemisorption between metal modified Y zeolite and thiophene and the reductive gases in coke oven gas on the thiophene adsorption performance still remains ambiguous. To address the aforementioned aims, series of NaMY (M = Ce, Ni, Zn and Ag) were prepared via ion-exchanged with Na + of NaY, and two comparable sets of thiophene adsorption evaluation were conducted in a fixed bed reactor: (1) NaY and NaMY were evaluated at different temperatures in simulated coke oven gas, and (2) NaCeY was evaluated in N 2 and different reductive atmospheres. The results show that NaNiY, NaZnY and NaAgY could adsorb thiophene via π-complexation, however, NaCeY mainly through S-Ce bond. Π complexation becomes weak above 150 °C, and the strength of S-Ce bond varies little when the temperature rises to 250 °C. Compared with that of other sorbents, the breakthrough adsorption capacity for thiophene ( Q b-thiophene ) of NaAgY reaches the highest 144 mg/g at 100 °C, but decreases sharply when temperature rises to 200 °C. NaCeY has relatively low variation in Q b-thiophene from 100 °C to 200 °C. Moreover, Ce(IV) in NaCeY is more favorable for thiophene adsorption than Ce(III) in coke oven gas and the presence of H 2 and CO would reduce the desulfurization activity of NaCeY. For the industrial utilization of thiophene ultra-deep removal, NaAgY has an excellent potential below 150 °C, while NaCeY with more Ce(IV) has a good prospect at 150–250 °C.

Suggested Citation

  • Fanjing Wei & Xiaoqin Guo & Weiren Bao & Liping Chang & Junjie Liao, 2022. "Metal Modified NaY Zeolite as Sorbent for the Ultra-Deep Removal of Thiophene in Simulated Coke Oven Gas," Energies, MDPI, vol. 15(7), pages 1-16, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:7:p:2620-:d:786398
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    References listed on IDEAS

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    1. Elham S. Moosavi & Seyed A. Dastgheib & Ramin Karimzadeh, 2012. "Adsorption of Thiophenic Compounds from Model Diesel Fuel Using Copper and Nickel Impregnated Activated Carbons," Energies, MDPI, vol. 5(10), pages 1-18, October.
    2. Arda Hatunoglu & Alessandro Dell’Era & Luca Del Zotto & Andrea Di Carlo & Erwin Ciro & Enrico Bocci, 2021. "Deactivation Model Study of High Temperature H 2 S Wet-Desulfurization by Using ZnO," Energies, MDPI, vol. 14(23), pages 1-14, December.
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