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A Model for Predicting Arsenic Volatilization during Coal Combustion Based on the Ash Fusion Temperature and Coal Characteristic

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  • Bo Zhao

    (Hubei Provincial Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Geng Chen

    (Hubei Provincial Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Zijiang Xiong

    (Hubei Provincial Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Linbo Qin

    (Hubei Provincial Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Wangsheng Chen

    (Hubei Provincial Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Jun Han

    (Industrial Safety Engineering Technology Research Center of Hubei Province, Wuhan University of Science and Technology, Wuhan 430081, China)

Abstract

Arsenic emission from coal combustion power plants has attracted increasing attention due to its high toxicity. In this study, it was found that there was a close relationship between the ash fusion temperature (AFT) and arsenic distribution based on the thermodynamic equilibrium calculation. In addition to the AFT, coal characteristics and combustion temperature also considerably affected the distribution and morphology of arsenic during coal combustion. Thus, an arsenic volatilization model based on the AFT, coal type, and combustion temperature during coal combustion was developed. To test the accuracy of the model, blending coal combustion experiments were carried out. The experimental results and published data proved that the developed arsenic volatilization model can accurately predict arsenic emission during co-combustion, and the errors of the predicted value for bituminous and lignite were 2.3–9.8%, with the exception of JingLong (JL) coal when combusted at 1500 °C.

Suggested Citation

  • Bo Zhao & Geng Chen & Zijiang Xiong & Linbo Qin & Wangsheng Chen & Jun Han, 2021. "A Model for Predicting Arsenic Volatilization during Coal Combustion Based on the Ash Fusion Temperature and Coal Characteristic," Energies, MDPI, vol. 14(2), pages 1-11, January.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:2:p:334-:d:477451
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    Citations

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    Cited by:

    1. Oksana Marinina & Marina Nevskaya & Izabela Jonek-Kowalska & Radosław Wolniak & Mikhail Marinin, 2021. "Recycling of Coal Fly Ash as an Example of an Efficient Circular Economy: A Stakeholder Approach," Energies, MDPI, vol. 14(12), pages 1-21, June.
    2. Jaroslaw Krzywanski & Wojciech Nowak & Karol Sztekler, 2022. "Novel Combustion Techniques for Clean Energy," Energies, MDPI, vol. 15(13), pages 1-3, June.

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