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sp 2 –sp 3 Hybrid Porous Carbon Materials Applied for Supercapacitors

Author

Listed:
  • Ji Su Chae

    (Energy & Environmental Division, Korea Institute of Ceramic Engineering & Technology, Jinju-si 52851, Korea)

  • Won-seop Kang

    (Vina Tech Co., Ltd., Jeonju-si 54853, Jeollabuk-do, Korea)

  • Kwang Chul Roh

    (Energy & Environmental Division, Korea Institute of Ceramic Engineering & Technology, Jinju-si 52851, Korea)

Abstract

Carbon materials have gained considerable attention in recent years due to their superior properties. Activated carbon has been used in supercapacitors due to its density and rapid adsorption capability. The sp 2 –sp 3 hybrid porous carbon materials are synthesized using herringbone-type carbon nanofibers (CNFs) and carbonized spherical phenol resins, with KOH as the activating agent. The morphology of the hybrid porous carbon facilitates the formation of ribbon-like nanosheets from highly activated CNFs wrapped around spherical resin-based activated carbon. The etching and separation of the CNFs produce a thin ribbon-like nanosheet structure; these CNFs simultaneously form new bonds with activated carbon, forming the sp 2 –sp 3 hybrid porous structure. The relatively poor electrical conductivity of amorphous carbon is improved by the 3D conductive network that interconnects the CNF and amorphous carbon without requiring additional conductive material. The composite electrode has high electron conductivity and a large surface area with a specific capacitance of 120 F g −1 . Thus, the strategy substantially simplifies the hybrid materials of sp 2 -hybridized CNFs and sp 3 -hybridized amorphous spherical carbon and significantly improves the comprehensive electrochemical performance of supercapacitors. The developed synthesis strategy provides important insights into the design and fabrication of carbon nanostructures that can be potentially applied as electrode materials for supercapacitors.

Suggested Citation

  • Ji Su Chae & Won-seop Kang & Kwang Chul Roh, 2021. "sp 2 –sp 3 Hybrid Porous Carbon Materials Applied for Supercapacitors," Energies, MDPI, vol. 14(19), pages 1-9, September.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:19:p:5990-:d:640236
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    References listed on IDEAS

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    1. Dmitry V. Kosynkin & Amanda L. Higginbotham & Alexander Sinitskii & Jay R. Lomeda & Ayrat Dimiev & B. Katherine Price & James M. Tour, 2009. "Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons," Nature, Nature, vol. 458(7240), pages 872-876, April.
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