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The Prospects for Processing Reservoir Oil Sludge into Hydrocarbons by Low-Temperature Hydrogenation in Sorbing Electrochemical Matrices in Comparison with Conventional High-Temperature Hydrocracking

Author

Listed:
  • Anton Maximov

    (1Federal State Budgetary Institution of Science A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow 119991, Russia)

  • Aslan Tsivadze

    (2Federal State Budgetary Institution of Science A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia)

  • Alexander Fridman

    (2Federal State Budgetary Institution of Science A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia)

  • Tatyana Kuchinskaya

    (1Federal State Budgetary Institution of Science A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow 119991, Russia)

  • Alexander Novikov

    (2Federal State Budgetary Institution of Science A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia)

  • Maxim Shabanov

    (2Federal State Budgetary Institution of Science A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia)

  • Evgeny Naranov

    (1Federal State Budgetary Institution of Science A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow 119991, Russia)

Abstract

In this paper, we developed an effective method for purifying oil sludge using a sorbing electrochemical matrix and assessed the prospects of this method in comparison with conventional hydrocracking. We synthesized Ni-W supported hydrocracking catalysts with different morphology and studied their activity under various conditions, we compared the obtained catalysts with commercial catalyst SGK-5. We demonstrated that the introduction of a secondary mesoporous structure in the catalyst leads to an increase in the yield of light fractions to 52 wt.%. The possibility is demonstrated to obtain hydrocarbons from reservoir oil sludge, dispersed into an aqueous solution of detergent, by the method of low-temperature hydrogenation in sorbing electrochemical matrices. The obtained product was characterized by low viscosity, low content of transition metals (<320 ppm), and sulphur (<260 ppm).

Suggested Citation

  • Anton Maximov & Aslan Tsivadze & Alexander Fridman & Tatyana Kuchinskaya & Alexander Novikov & Maxim Shabanov & Evgeny Naranov, 2020. "The Prospects for Processing Reservoir Oil Sludge into Hydrocarbons by Low-Temperature Hydrogenation in Sorbing Electrochemical Matrices in Comparison with Conventional High-Temperature Hydrocracking," Energies, MDPI, vol. 13(20), pages 1-12, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:20:p:5362-:d:428159
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    Cited by:

    1. Oleg A. Kolenchukov & Kirill A. Bashmur & Vladimir V. Bukhtoyarov & Sergei O. Kurashkin & Vadim S. Tynchenko & Elena V. Tsygankova & Roman B. Sergienko & Vladislav V. Kukartsev, 2022. "Experimental Study of Oil Non-Condensable Gas Pyrolysis in a Stirred-Tank Reactor for Catalysis of Hydrogen and Hydrogen-Containing Mixtures Production," Energies, MDPI, vol. 15(22), pages 1-16, November.

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