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Functional Energy Accumulation, Photo- and Magnetosensitive Hybridity in the GaSe-Based Hierarchical Structures

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  • Piotr Chabecki

    (Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland)

  • Dariusz Całus

    (Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland)

  • Fedir Ivashchyshyn

    (Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland
    Institute of Applied Mathematics and Fundamental Sciences, Lviv Polytechnic National University, Bandera Str. 12, 79013 Lviv, Ukraine)

  • Anna Pidluzhna

    (Institute of Applied Mathematics and Fundamental Sciences, Lviv Polytechnic National University, Bandera Str. 12, 79013 Lviv, Ukraine)

  • Orest Hryhorchak

    (Theoretical Physics Department, Ivan Franko Lviv National University, 8 street Cyril and Methodius, 79005 Lviv, Ukraine)

  • Ihor Bordun

    (Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland
    Institute of Applied Mathematics and Fundamental Sciences, Lviv Polytechnic National University, Bandera Str. 12, 79013 Lviv, Ukraine)

  • Oleksandr Makarchuk

    (Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland
    Institute of Applied Mathematics and Fundamental Sciences, Lviv Polytechnic National University, Bandera Str. 12, 79013 Lviv, Ukraine)

  • Andriy V. Kityk

    (Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland)

Abstract

We report on the complex GaSe-based hierarchical structures GaSe(CS(NH 2 ) 2 ), GaSe(SmCl 3 ) and GaSe(CS(NH 2 ) 2 (SmCl 3 )) synthesized by an intercalation method. The conductive properties of synthesized clathrates and their relation to hierarchical structural complexity were explored by an impedance spectroscopy technique. The impedance response, thermostimulated discharge spectra, and photo- and magnetoresistive effects are reported. Based on the obtained results, the impurity energy spectra were calculated. A strong low-frequency inductive response, observable in the GaSe(SmCl 3 ) clathrate, makes this material promising for the development of gyrator-free nanodelay lines potentially applicable in nanoelectronics. Hierarchical GaSe(CS(NH 2 ) 2 (SmCl 3 )) clathrate, on the other hand, reveals hysteresis of the current–voltage characteristics, apparently confirming an accumulation of electric energy at interphase boundaries. A relevant spin battery effect, observable experimentally in stationary magnetic fields, demonstrates a principal possibility of the electric energy accumulation at a quantum level.

Suggested Citation

  • Piotr Chabecki & Dariusz Całus & Fedir Ivashchyshyn & Anna Pidluzhna & Orest Hryhorchak & Ihor Bordun & Oleksandr Makarchuk & Andriy V. Kityk, 2020. "Functional Energy Accumulation, Photo- and Magnetosensitive Hybridity in the GaSe-Based Hierarchical Structures," Energies, MDPI, vol. 13(17), pages 1-16, August.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:17:p:4321-:d:401767
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    References listed on IDEAS

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    1. Pham Nam Hai & Shinobu Ohya & Masaaki Tanaka & Stewart E. Barnes & Sadamichi Maekawa, 2009. "Electromotive force and huge magnetoresistance in magnetic tunnel junctions," Nature, Nature, vol. 458(7237), pages 489-492, March.
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