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Exploring Vinyl Polymers as Soft Carbon Precursors for M-Ion (M = Na, Li) Batteries and Hybrid Capacitors

Author

Listed:
  • Afshin Pendashteh

    (Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, 01510 Vitoria-Gasteiz, Spain)

  • Brahim Orayech

    (Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, 01510 Vitoria-Gasteiz, Spain)

  • Jon Ajuria

    (Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, 01510 Vitoria-Gasteiz, Spain)

  • María Jáuregui

    (Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, 01510 Vitoria-Gasteiz, Spain)

  • Damien Saurel

    (Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, 01510 Vitoria-Gasteiz, Spain)

Abstract

The viability of the sodium-ion batteries as a post-lithium storage technology is strongly tied to the development of high-performance carbonaceous anode materials. This requires screening novel precursors, and tuning their electrochemical properties. Soft carbons as promising anode materials, not only for batteries, but also in hybrid capacitors, have drawn great attention, due to safe operation voltage and high-power properties. Herein, several vinyl polymer-derived soft carbons have been prepared via pyrolysis, and their physicochemical and sodium storage properties have been evaluated. According to the obtained results, vinyl polymers are a promising source for preparation of soft carbon anode materials for sodium-ion battery application. In addition, their applicability towards Li-ion battery and hybrid capacitors (e.g., Li ion capacitors, LICs) has been examined. This work not only contrasts the carbonization products of these polymers with relevant physicochemical characterization, but also screens potential precursors for soft carbons with interesting alkali metal-ion (e.g., Na or Li, with an emphasis on Na) storage properties. This can stimulate further research to tune and improve the electrochemical properties of the soft carbons for energy storage applications.

Suggested Citation

  • Afshin Pendashteh & Brahim Orayech & Jon Ajuria & María Jáuregui & Damien Saurel, 2020. "Exploring Vinyl Polymers as Soft Carbon Precursors for M-Ion (M = Na, Li) Batteries and Hybrid Capacitors," Energies, MDPI, vol. 13(16), pages 1-13, August.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:16:p:4189-:d:398503
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    Cited by:

    1. Francesca Lionetto & Sonia Bagheri & Claudio Mele, 2021. "Sustainable Materials from Fish Industry Waste for Electrochemical Energy Systems," Energies, MDPI, vol. 14(23), pages 1-19, November.

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