IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v12y2019i20p3885-d276379.html
   My bibliography  Save this article

Boosting Hydrogen Production from Formic Acid over Pd Catalysts by Deposition of N-Containing Precursors on the Carbon Support

Author

Listed:
  • Fedor S. Golub

    (Laboratory of Catalytic Methods of Solar Energy Transformation, Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia
    Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russia)

  • Sergey Beloshapkin

    (Bernal Institute, University of Limerick, V94 T9PX Limerick, Ireland)

  • Artem V. Gusel’nikov

    (Laboratory of Physico-Chemistry of Nanomaterials, Nikolaev Institute of Inorganic Chemistry, SB RAS, 630090 Novosibirsk, Russia)

  • Vasily A. Bolotov

    (Laboratory of Catalytic Methods of Solar Energy Transformation, Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia)

  • Valentin N. Parmon

    (Laboratory of Catalytic Methods of Solar Energy Transformation, Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia
    Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russia)

  • Dmitri A. Bulushev

    (Laboratory of Catalytic Methods of Solar Energy Transformation, Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia
    Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russia)

Abstract

Formic acid is a promising liquid organic hydrogen carrier (LOHC) since it has relatively high hydrogen content (4.4 wt%), low inflammability, low toxicity and can be obtained from biomass or from CO 2 . The aim of the present research was the creation of efficient 1 wt% Pd catalysts supported on mesoporous graphitic carbon (Sibunit) for the hydrogen production from gas-phase formic acid. For this purpose, the carbon support was modified by pyrolysis of deposited precursors containing pyridinic nitrogen such as melamine (Mel), 2,2′-bipyridine (Bpy) or 1,10-phenanthroline (Phen) at 673 K. The following activity trend of the catalysts Pd/Mel/C > Pd/C ~ Pd/Bpy/C > Pd/Phen/C was obtained. The activity of the Pd/Mel/C catalyst was by a factor of 4 higher than the activity of the Pd/C catalyst at about 373 K and the apparent activation energy was significantly lower than those for the other catalysts (32 vs. 42–46 kJ/mol). The high activity of the melamine-based samples was explained by a high dispersion of Pd nanoparticles (~2 nm, HRTEM) and their strong electron-deficient character (XPS) provided by interaction of Pd with pyridinic nitrogen species of the support. The presented results can be used for the development of supported Pd catalysts for hydrogen production from different liquid organic hydrogen carriers.

Suggested Citation

  • Fedor S. Golub & Sergey Beloshapkin & Artem V. Gusel’nikov & Vasily A. Bolotov & Valentin N. Parmon & Dmitri A. Bulushev, 2019. "Boosting Hydrogen Production from Formic Acid over Pd Catalysts by Deposition of N-Containing Precursors on the Carbon Support," Energies, MDPI, vol. 12(20), pages 1-13, October.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:20:p:3885-:d:276379
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/12/20/3885/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/12/20/3885/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Oh, Taek Hyun, 2016. "A formic acid hydrogen generator using Pd/C3N4 catalyst for mobile proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 112(C), pages 679-685.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Dmitri A. Bulushev, 2021. "Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol," Energies, MDPI, vol. 14(20), pages 1-5, October.
    2. Alina D. Nishchakova & Dmitri A. Bulushev & Olga A. Stonkus & Igor P. Asanov & Arcady V. Ishchenko & Alexander V. Okotrub & Lyubov G. Bulusheva, 2019. "Effects of the Carbon Support Doping with Nitrogen for the Hydrogen Production from Formic Acid over Ni Catalysts," Energies, MDPI, vol. 12(21), pages 1-10, October.
    3. Arina N. Suboch & Olga Y. Podyacheva, 2021. "Pd Catalysts Supported on Bamboo-Like Nitrogen-Doped Carbon Nanotubes for Hydrogen Production," Energies, MDPI, vol. 14(5), pages 1-13, March.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ensafi, Ali A. & Nabiyan, Afshin & Jafari-Asl, Mehdi & Dinari, Mohammad & Farrokhpour, Hossein & Rezaei, B., 2016. "Galvanic exchange at layered doubled hydroxide/N-doped graphene as an in-situ method to fabricate powerful electrocatalysts for hydrogen evolution reaction," Energy, Elsevier, vol. 116(P1), pages 1087-1096.
    2. Tomonori Miyagawa & Mika Goto, 2022. "Hydrogen Production Cost Forecasts since the 1970s and Implications for Technological Development," Energies, MDPI, vol. 15(12), pages 1-24, June.
    3. Hong, Po & Xu, Liangfei & Li, Jianqiu & Ouyang, Minggao, 2017. "Modeling of membrane electrode assembly of PEM fuel cell to analyze voltage losses inside," Energy, Elsevier, vol. 139(C), pages 277-288.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:12:y:2019:i:20:p:3885-:d:276379. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.