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5-Hydroxymethylfurfural (5-HMF) Production from Hexoses: Limits of Heterogeneous Catalysis in Hydrothermal Conditions and Potential of Concentrated Aqueous Organic Acids as Reactive Solvent System

Author

Listed:
  • Rodrigo Lopes De Souza

    (Institut de Recherche sur la Catalyse et l’Environnement de Lyon, IRCELYON, CNRS, Université Lyon 1, 2 avenue Albert Einstein 69626 Villeurbanne, France)

  • Hao Yu

    (Institut de Recherche sur la Catalyse et l’Environnement de Lyon, IRCELYON, CNRS, Université Lyon 1, 2 avenue Albert Einstein 69626 Villeurbanne, France)

  • Franck Rataboul

    (Institut de Recherche sur la Catalyse et l’Environnement de Lyon, IRCELYON, CNRS, Université Lyon 1, 2 avenue Albert Einstein 69626 Villeurbanne, France)

  • Nadine Essayem

    (Institut de Recherche sur la Catalyse et l’Environnement de Lyon, IRCELYON, CNRS, Université Lyon 1, 2 avenue Albert Einstein 69626 Villeurbanne, France)

Abstract

5-Hydroxymethylfurfural (5-HMF) is an important bio-sourced intermediate, formed from carbohydrates such as glucose or fructose. The treatment at 150–250 °C of glucose or fructose in pure water and batch conditions, with catalytic amounts of most of the usual acid-basic solid catalysts, gave limited yields in 5-HMF, due mainly to the fast formation of soluble oligomers. Niobic acid, which possesses both Lewis and Brønsted acid sites, gave the highest 5-HMF yield, 28%, when high catalyst/glucose ratio is used. By contrast, we disclose in this work that the reaction of fructose in concentrated aqueous solutions of carboxylic acids, formic, acetic or lactic acids, used as reactive solvent media, leads to the selective dehydration of fructose in 5-HMF with yields up to 64% after 2 hours at 150 °C. This shows the potential of such solvent systems for the clean and easy production of 5-HMF from carbohydrates. The influence of adding solid catalysts to the carboxylic acid media was also reported, starting from glucose.

Suggested Citation

  • Rodrigo Lopes De Souza & Hao Yu & Franck Rataboul & Nadine Essayem, 2012. "5-Hydroxymethylfurfural (5-HMF) Production from Hexoses: Limits of Heterogeneous Catalysis in Hydrothermal Conditions and Potential of Concentrated Aqueous Organic Acids as Reactive Solvent System," Challenges, MDPI, vol. 3(2), pages 1-21, September.
    • Handle: RePEc:gam:jchals:v:3:y:2012:i:2:p:212-232:d:20051
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    Citations

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    Cited by:

    1. Morone, Amruta & Apte, Mayura & Pandey, R.A., 2015. "Levulinic acid production from renewable waste resources: Bottlenecks, potential remedies, advancements and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 548-565.
    2. Kang, Shimin & Fu, Jinxia & Zhang, Gang, 2018. "From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 340-362.
    3. Ramy Gamgoum & Animesh Dutta & Rafael M. Santos & Yi Wai Chiang, 2016. "Hydrothermal Conversion of Neutral Sulfite Semi-Chemical Red Liquor into Hydrochar," Energies, MDPI, vol. 9(6), pages 1-18, June.
    4. Subhash Paul & Animesh Dutta & Fantahun Defersha, 2018. "Mechanical and Alkaline Hydrothermal Treated Corn Residue Conversion in to Bioenergy and Biofertilizer: A Resource Recovery Concept," Energies, MDPI, vol. 11(3), pages 1-20, February.
    5. Hu, Lei & Wu, Zhen & Jiang, Yetao & Wang, Xiaoyu & He, Aiyong & Song, Jie & Xu, Jiming & Zhou, Shouyong & Zhao, Yijiang & Xu, Jiaxing, 2020. "Recent advances in catalytic and autocatalytic production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    6. Kambo, Harpreet Singh & Dutta, Animesh, 2015. "A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 359-378.

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