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Highly Porous and Nutrients-Rich Biochar Derived from Dairy Cattle Manure and Its Potential for Removal of Cationic Compound from Water

Author

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  • Wen-Tien Tsai

    (Graduate Institute of Bioresources, National Pingtung University of Science and Technology, Pingtung 912, Taiwan)

  • Chien-Hung Hsu

    (Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, Pingtung 912, Taiwan)

  • Yu-Quan Lin

    (Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, Pingtung 912, Taiwan)

Abstract

The use of biochar in the horticulture and crop fields is a recent method to improve soil fertility due to its porous features and rich nutrients. In the present study, dairy manure (DM) was used as a biomass precursor in the preparation of highly porous biochar (DM-BC) produced at specific conditions. Based on N 2 adsorption-desorption isotherms and scanning electron microscopy (SEM) observations, the resulting biochar featured its microporous/mesoporous textures with a BET surface area of about 300 m 2 /g and total pore volume of 0.185 cm 3 /g, which could be a low-cost biosorbent for the effective removal of methylene blue (MB) from the aqueous solution. As observed by the energy dispersive X-ray spectroscopy (EDS), the primary inorganic nutrients on the surface of DM-BC included calcium (Ca), magnesium (Mg), potassium (K), phosphorus (P), silicon (Si), sulfur (S), sodium (Na) and aluminum (Al). Furthermore, the resulting biochar was investigated in duplicate for its biosorption performance of cationic compound (i.e., methylene blue, MB) from the aqueous solution with various initial MB concentrations and DM-BC dosages at 25 °C. The findings showed that the biosorption kinetic parameters fitted by the pseudo-second order rate model with high correlations were consistent with its porous features. These experimental results suggested that the porous DM-based biochar could be reused as a biosorbent, biofertilizer, or soil amendments due to the high porosity and the abundance in nutrient minerals.

Suggested Citation

  • Wen-Tien Tsai & Chien-Hung Hsu & Yu-Quan Lin, 2019. "Highly Porous and Nutrients-Rich Biochar Derived from Dairy Cattle Manure and Its Potential for Removal of Cationic Compound from Water," Agriculture, MDPI, vol. 9(6), pages 1-9, June.
    • Handle: RePEc:gam:jagris:v:9:y:2019:i:6:p:114-:d:236608
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    References listed on IDEAS

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    1. Britta Bergfeldt & Marco Tomasi Morgano & Hans Leibold & Frank Richter & Dieter Stapf, 2018. "Recovery of Phosphorus and other Nutrients during Pyrolysis of Chicken Manure," Agriculture, MDPI, vol. 8(12), pages 1-10, November.
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    Cited by:

    1. Sadaf Hashmi & Uzma Younis & Subhan Danish & Tariq Muhammad Munir, 2019. "Pongamia pinnata L. Leaves Biochar Increased Growth and Pigments Syntheses in Pisum sativum L. Exposed to Nutritional Stress," Agriculture, MDPI, vol. 9(7), pages 1-13, July.
    2. Struhs, Ethan & Mirkouei, Amin & You, Yaqi & Mohajeri, Amir, 2020. "Techno-economic and environmental assessments for nutrient-rich biochar production from cattle manure: A case study in Idaho, USA," Applied Energy, Elsevier, vol. 279(C).

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