IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v208y2025ics1364032124007263.html
   My bibliography  Save this article

Low-temperature and reversible hydrogen storage advances of light metal borohydrides

Author

Listed:
  • Wang, Shun
  • Li, Zhenglong
  • Gao, Mingxia
  • Liu, Yongfeng
  • Pan, Hongge

Abstract

Solid-state light metal borohydrides represented by LiBH4, NaBH4, Mg(BH4)2, and Ca(BH4)2 with high hydrogen capacity are promising media to store and transport hydrogen safely and efficiently, raising a hope for popularizing electricity-hydrogen coupling systems built on clean and renewable energy. Yet stable thermodynamics and sluggish kinetics of light metal borohydrides remain two key issues to be addressed for achieving the rapid and reversible hydrogen desorption and absorption under mild conditions. In this review, the short introductions for basic hydrogen storage characteristics of light metal borohydrides and fundamental principles of common thermodynamic and kinetic modification strategies are first presented. Then the focus is on the research advances in reducing operation temperature, accelerating reaction rates, and enhancing cyclic reversibility of light metal borohydrides by using these strategies or their synergy. On this basis, the existing challenges and future directions on light metal borohydrides are proposed from novel and specific perspectives, aiming to obtain high performance hydrogen storage materials practically available towards electricity-hydrogen coupling systems.

Suggested Citation

  • Wang, Shun & Li, Zhenglong & Gao, Mingxia & Liu, Yongfeng & Pan, Hongge, 2025. "Low-temperature and reversible hydrogen storage advances of light metal borohydrides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 208(C).
  • Handle: RePEc:eee:rensus:v:208:y:2025:i:c:s1364032124007263
    DOI: 10.1016/j.rser.2024.115000
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032124007263
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.rser.2024.115000?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:208:y:2025:i:c:s1364032124007263. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.