IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v65y2014icp92-101.html
   My bibliography  Save this article

Effect of Pd, Ru, Ni and ceramic supports on selective deoxygenation and hydrogenation of fast pyrolysis Jatropha residue vapors

Author

Listed:
  • Kaewpengkrow, Prangtip
  • Atong, Duangduen
  • Sricharoenchaikul, Viboon

Abstract

Catalytic upgrading of the pyrolytic vapors after fast pyrolysis of Jatropha residue was performed using analytical pyrolysis–gas chromatography/mass spectrometry (Py–GC/MS) at 673–873 K. The Py–GC/MS analyses for pyrolysis vapors show a range of aromatic hydrocarbons, hydrocarbon compounds, phenols, alcohols, aldehydes, ketones, acids and esters, furan and N-containing compounds. The result showed that high temperature had positive influence on the yields of pyrolytic products. Catalytic testing was performed by using Al2O3, ZrO2 based catalysts and their modified ones with impregnation of Pd, Ru, and Ni, respectively. The Al2O3 and ZrO2 were impregnated with CeO2 to promote metal dispersion prior to deposition of Pd, Ru, or Ni. From the experiment, these catalysts showed some potential to convert the highly oxygenated compounds to aromatic and hydrocarbons. The hydrocarbon yields increased with increasing catalyst to Jatropha ratio in all catalysts. The hydrocarbon selectivity was Ni–Ce/Al2O3 > Al2O3 > Ce/Al2O3 > Pd–Ce/Al2O3 > Ru–Ce/Al2O3 in Jatropha to catalyst ratio of 1:5. Pd–Ce/Al2O3 was the most effective in terms of increased aromatic and hydrocarbon compounds, decreased oxygenated and N-compounds. Though Al2O3 increased favorable aromatic and hydrocarbon compounds with completely elimination of acid but it also promoted adverse N-containing compounds. Activities of Ru–Ce/Al2O3 were similar to Ce/Al2O3 except for the selectivity toward acid compounds. Comparing to ZrO2 catalysts, all Al2O3 based catalysts displayed relatively higher activity toward deoxygenation reactions which resulted in low quantity of carboxylic acids and other oxygenated compounds while enhanced yields of aliphatic and aromatic hydrocarbons. Al2O3 had surface area of 103.38 m2/g while surface area of ZrO2 was 12 m2/g, indicating that catalyst with high surface area had better catalytic activity. However, Al2O3 catalysts seemed to promote N-compounds suggesting that further denitrogenation is required while pyrolysis with ZrO2 had disadvantage on high yield of acid which could cause the corrosion problem. Nevertheless, overall performances of these two support catalysts are acceptable and can be considered as good candidates for bio-oil upgrading catalysts.

Suggested Citation

  • Kaewpengkrow, Prangtip & Atong, Duangduen & Sricharoenchaikul, Viboon, 2014. "Effect of Pd, Ru, Ni and ceramic supports on selective deoxygenation and hydrogenation of fast pyrolysis Jatropha residue vapors," Renewable Energy, Elsevier, vol. 65(C), pages 92-101.
  • Handle: RePEc:eee:renene:v:65:y:2014:i:c:p:92-101
    DOI: 10.1016/j.renene.2013.07.026
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148113003716
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2013.07.026?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    2. Nishu, & Li, Chong & Chai, Meiyun & Rahman, Md. Maksudur & Li, Yingkai & Sarker, Manobendro & Liu, Ronghou, 2021. "Performance of alkali and Ni-modified ZSM-5 during catalytic pyrolysis of extracted hemicellulose from rice straw for the production of aromatic hydrocarbons," Renewable Energy, Elsevier, vol. 175(C), pages 936-951.
    3. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    4. Vichaphund, Supawan & Aht-ong, Duangdao & Sricharoenchaikul, Viboon & Atong, Duangduen, 2015. "Production of aromatic compounds from catalytic fast pyrolysis of Jatropha residues using metal/HZSM-5 prepared by ion-exchange and impregnation methods," Renewable Energy, Elsevier, vol. 79(C), pages 28-37.
    5. Kabir, G. & Hameed, B.H., 2017. "Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 945-967.
    6. Navarro-Pineda, Freddy S. & Baz-Rodríguez, Sergio A. & Handler, Robert & Sacramento-Rivero, Julio C., 2016. "Advances on the processing of Jatropha curcas towards a whole-crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 247-269.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:65:y:2014:i:c:p:92-101. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.