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One-pot conversion of glucose to 5-hydroxymethylfurfural under aqueous conditions using acid/base bifunctional mesoporous silica catalyst

Author

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  • Modak, Arindam
  • Mankar, Akshay R.
  • Sonde, R.R.
  • Pant, Kamal K.

Abstract

One-pot conversion of carbohydrate-derived biomass compounds to 5-hydroxymethylfurfural (HMF) using an environmentally green solvent such as water is meritorious, yet challenging, which requires the strategic design of catalysts. We prepare an ordered bifunctional organocatalyst (MS-AB) containing 3-aminopropylacetic acid grafted within the silica nanocage that converts glucose-to-HMF, exhibiting the highest HMF yield (60 wt.%/85.7 mol%) in water and under microwave conditions. Moreover, the calculated activation energies (150–170 °C) for glucose isomerization to fructose, vis-à-vis dehydration to HMF were 59.06 and 138.05 kJ mol−1, respectively which can even be comparable with the metal-catalyzed reactions. Further evidence was shown from the rate constant values, indicating fructose dehydration is faster (rate constant: k2: 1.92 x 10−2 to 1.13 x 10−1 min−1) than glucose isomerization (rate constant: k1: 2.5 to 5.3 x 10−3 min−1). Considering the advantages associated with MS-AB, the results might showcase the potential of organocatalyst for sustainable utilization of lignocellulosic biomass to platform chemicals.

Suggested Citation

  • Modak, Arindam & Mankar, Akshay R. & Sonde, R.R. & Pant, Kamal K., 2023. "One-pot conversion of glucose to 5-hydroxymethylfurfural under aqueous conditions using acid/base bifunctional mesoporous silica catalyst," Renewable Energy, Elsevier, vol. 212(C), pages 97-110.
    • Handle: RePEc:eee:renene:v:212:y:2023:i:c:p:97-110
    DOI: 10.1016/j.renene.2023.05.058
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    References listed on IDEAS

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    1. Wan, Jinquan & Lian, Jie & Wang, Yan & Ma, Yongwen, 2015. "Investigation of cellulose supramolecular structure changes during conversion of waste paper in near-critical water on producing 5-hydroxymethyl furfural," Renewable Energy, Elsevier, vol. 80(C), pages 132-139.
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    Cited by:

    1. Fang, Juan & Dong, Hao & Xu, Haimei, 2023. "The effect of Lewis acidity of tin loading siliceous MCM-41 on glucose conversion into 5-hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 218(C).

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