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The thermodynamics of discontinuous orientational phase transitions in quantum crystals

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Listed:
  • Sprik, M.
  • Nijman, A.J.
  • Trappeniers, N.J.

Abstract

Generalized Clausius-Clapeyron relations are derived for discontinuous orientational phase transitions in the quantum-mechanical regime. Some qualitative features of the isotope effect on the transition temperature are explained. The quantum correction to the density dependence of the h.c.p.-f.c.c. transition temperature in solid hydrogen, the stability of the partially ordered phase of solid CH4 and the anomalous isotope effect in ammonium bromide are treated in thermodynamic terms.

Suggested Citation

  • Sprik, M. & Nijman, A.J. & Trappeniers, N.J., 1979. "The thermodynamics of discontinuous orientational phase transitions in quantum crystals," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 98(1), pages 231-244.
    • Handle: RePEc:eee:phsmap:v:98:y:1979:i:1:p:231-244
    DOI: 10.1016/0378-4371(79)90175-4
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    References listed on IDEAS

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    1. Russell G. Thompson & J. Michael Sprott & Richard W. Callen, 1972. "Demand, Supply, and Price Relationships for the Broiler Sector, with Emphasis on the Jack-Knife Method," American Journal of Agricultural Economics, Agricultural and Applied Economics Association, vol. 54(2), pages 245-248.
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