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Use of accurate diffusion and second virial coefficients to determine (m, 6, 8) potential parameters for nine binary noble gas systems

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  • Arora, P.S.
  • Robjohns, H.L.
  • Dunlop, Peter J.

Abstract

Using accurate binary diffusion coefficients obtained over a temperature range of 275 to 323 K, together with some excellent second virial coefficients in the literature, (m, 6, 8) potential parameters have been obtained for the systems He-Ne, He-Ar, He-Kr, He-Xe, Ne-Ar, Ne-Kr, Ne-Xe, Ar-Kr and Ar-Xe. These parameters accurately predict all the precise binary transport properties which have been reported for these systems, some over a range of 1400 K. The present analysis indicates that these mixtures are not conformal with any one of the assumed (m, 6, 8) group of potentials.

Suggested Citation

  • Arora, P.S. & Robjohns, H.L. & Dunlop, Peter J., 1979. "Use of accurate diffusion and second virial coefficients to determine (m, 6, 8) potential parameters for nine binary noble gas systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 95(3), pages 561-571.
    • Handle: RePEc:eee:phsmap:v:95:y:1979:i:3:p:561-571
    DOI: 10.1016/0378-4371(79)90032-3
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    References listed on IDEAS

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    1. Watanabe, Fukutaro, 1970. "Economic Growth and the Foreign Reserve Policy (in Japanese)," Economic Review, Hitotsubashi University, vol. 21(2), pages 178-185, May.
    2. P.C. Joshi, 1963. "The Decline of Indigenous Handicrafts in Uttar Pradesh," The Indian Economic & Social History Review, , vol. 1(1), pages 24-35, July.
    3. D.N. Saxena, 1976. "Current Economic Setting and the Challenge of Development Planning," Foreign Trade Review, , vol. 11(1), pages 1-20, April.
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    1. Dunlop, Peter J. & Bignell, C.M., 1990. "The tracer diffusion coefficient of Kr85 in gaseous argon at 300 K," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 165(3), pages 370-374.
    2. Najafi, B. & Mason, E.A. & Kestin, J., 1983. "Improved corresponding states principle for the noble gases," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 119(3), pages 387-440.
    3. Dunlop, Peter J. & Bignell, C.M. & Taylor, W.L., 1989. "Diffusion in three binary gaseous systems containing neon isotopes at 300 K," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 157(3), pages 1259-1260.
    4. Trengove, R.D. & Robjohns, H.L. & Bell, T.N. & Martin, M.L. & Dunlop, Peter J., 1981. "Thermal diffusion factors at 300 K for seven binary noble gas systems containing helium or neon," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 108(2), pages 488-501.
    5. Trengove, R.D. & Dunlop, Peter J., 1982. "Diffusion coefficients and thermal diffusion factors for five binary systems of nitrogen and a noble gas," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 115(3), pages 339-352.
    6. Trengove, R.D. & Harris, K.R. & Robjohns, H.L. & Dunlop, Peter J., 1985. "Diffusion and thermal diffusion in some dilute binary gaseous systems between 195 and 400 K: Tests of several asymmetric potentials using the infinite order sudden approximation," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 131(3), pages 506-519.
    7. Trengove, R.D. & Robjohns, H.L. & Martin, M.L. & Dunlop, Peter J., 1981. "The pressure dependences of the thermal diffusion factors of the systems He-Ar, He-CO6 at 300 K," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 108(2), pages 502-510.
    8. Shankland, Ian R. & Dunlop, Peter J., 1980. "Pressure dependence of the mutual diffusion coefficients of the binary systems N2 + Ar, N2 + O2, O2 + Ar and Ar + Kr at 300 and 323 K," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 100(1), pages 64-84.

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