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The influence of chain-flexibility on the colligative properties of polyelectrolyte solutions

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  • Odijk, Theo
  • Mandel, M.

Abstract

The neglect of chain flexibility in Manning's theory of polyelectrolytes is assessed. For a flexible polyelectrolyte-the uniformly charged wormlike chain-counterion condensation is unaffected but colligative properties need to be modified. The relevant dimensionless parameter is (κLT)-1 where κ-1 is the Debye-Hückel radius and LT is the sum of the bare and electrostatic persistence lengths.

Suggested Citation

  • Odijk, Theo & Mandel, M., 1978. "The influence of chain-flexibility on the colligative properties of polyelectrolyte solutions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 93(1), pages 298-306.
    • Handle: RePEc:eee:phsmap:v:93:y:1978:i:1:p:298-306
    DOI: 10.1016/0378-4371(78)90223-6
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    1. Robert S. Woodward, 1973. "The Capital Bias of DREE Incentives," University of Western Ontario, Departmental Research Report Series 7315, University of Western Ontario, Department of Economics.
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