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Virial coefficients of the equation of state of a gas of nonspherical molecules II. Polar molecules

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  • Singh, S.
  • Singh, Y.

Abstract

The second and third virial coefficients of polar gases have been calculated for a set of force parameters which has been found suitable to explain the dilute gas viscosity data. The influence of a large number of orientation dependent pair- and three-body nonadditive interactions have been taken into account. The relative contribution of each branch of pair and triplet interactions has been evaluated as a function of temperature. The theoretical results have been compared with the experimental data of NH3 and CH3F.

Suggested Citation

  • Singh, S. & Singh, Y., 1977. "Virial coefficients of the equation of state of a gas of nonspherical molecules II. Polar molecules," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 87(2), pages 344-353.
    • Handle: RePEc:eee:phsmap:v:87:y:1977:i:2:p:344-353
    DOI: 10.1016/0378-4371(77)90021-8
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