IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v82y1975i3p319-351.html
   My bibliography  Save this article

Critical exponents at the turn of the century

Author

Listed:
  • Levelt Sengers, J.M.H

Abstract

The notion of a critical exponent was first used by Van der Waals in 1893 for describing the critical behavior of the surface tension. He also noticed in the early 1890's that experimental data on capillarity indicated a nonclassical value for the surface tension exponent. Verschaffelt found that this was due to the fact that the coexistence curve exponent beta was nonclassical. In 1900, he established precise nonclassical values for the exponents beta and delta. Even though from this time onwards the “cubic law” for fluid coexistence curves was accepted, the true implication of Verschaffelt's results, namely the failure of classical theory, was not appreciated. Some reasons for this lack of impact will be given.

Suggested Citation

  • Levelt Sengers, J.M.H, 1975. "Critical exponents at the turn of the century," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 82(3), pages 319-351.
  • Handle: RePEc:eee:phsmap:v:82:y:1975:i:3:p:319-351
    DOI: 10.1016/0378-4371(76)90012-1
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/0378437176900121
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

    File URL: https://libkey.io/10.1016/0378-4371(76)90012-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sengers, J.V. & Bedeaux, D. & Mazur, P. & Greer, S.C., 1980. "Behavior of the dielectric constant of fluids near a critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 104(3), pages 573-594.
    2. Trappeniers, N.J. & Boots, H.M.J. & Huijser, R.H. & Michels, A.C., 1980. "Investigation of multiple scattering contributions to the depolarization of light scattered by xenon and carbon dioxide in the critical region," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 103(3), pages 455-467.
    3. Boots, H.M.J. & Bedeaux, D. & Mazur, P., 1976. "On the theory of multiple scattering II. Critical scattering," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 84(2), pages 217-255.
    4. Sengers, J.V. & Van Leeuwen, J.M.J., 1982. "Nonlocal gravity-induced density profiles in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 116(3), pages 345-367.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:82:y:1975:i:3:p:319-351. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.