IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v510y2018icp233-242.html
   My bibliography  Save this article

Phase behavior of hard spheres mixed with supramolecular polymers

Author

Listed:
  • Peters, Vincent F.D.
  • Tuinier, Remco

Abstract

We present a theory that predicts the phase behavior of hard spheres (HS) mixed with non-adsorbing supramolecular polymers in a common solvent. It combines Generalized Free Volume Theory with a mean-field model for equilibrium polymers in solution extended with scaling theory to incorporate excluded volume effects in a good solvent. The system displays similar phase stability as conventional HS-polymer mixtures, although there is a small preference for gas–liquid coexistence with respect to fluid–crystal equilibrium in the case of a HS-supramolecular polymer mixture. Phase transitions can be induced by external stimuli such as temperature or light due to the stimuli-responsive nature of the supramolecular polymer size.

Suggested Citation

  • Peters, Vincent F.D. & Tuinier, Remco, 2018. "Phase behavior of hard spheres mixed with supramolecular polymers," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 510(C), pages 233-242.
  • Handle: RePEc:eee:phsmap:v:510:y:2018:i:c:p:233-242
    DOI: 10.1016/j.physa.2018.06.108
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S037843711830832X
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

    File URL: https://libkey.io/10.1016/j.physa.2018.06.108?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mao, Y. & Cates, M.E. & Lekkerkerker, H.N.W., 1995. "Depletion force in colloidal systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 222(1), pages 10-24.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Svit, K.A. & Zhuravlev, K.S. & Kireev, S.E. & Sabelfeld, K.K., 2024. "2D kinetic Monte-Carlo model of nanocrystal aggregation within a liquid matrix: Simulation and experimental study," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 641(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:510:y:2018:i:c:p:233-242. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.