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Single particle dynamics of a confined Lennard–Jones mixture in the supercooled regime

Author

Listed:
  • Gallo, P.
  • Pellarin, R.
  • Rovere, M.

Abstract

Dynamical properties of a supercooled Lennard–Jones binary mixture in a disordered array of soft spheres are studied by computer simulation close to the Mode Coupling Theory crossover temperature Tc. Predictions of the MCT are satisfied by the confined liquid. The b exponent of the von Schweidler law, the γ exponent and Tc are evaluated for both species. The range of validity of the theory shrinks and a substantial enhancement of hopping processes are observed above Tc with respect to the bulk.

Suggested Citation

  • Gallo, P. & Pellarin, R. & Rovere, M., 2002. "Single particle dynamics of a confined Lennard–Jones mixture in the supercooled regime," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 314(1), pages 530-538.
    • Handle: RePEc:eee:phsmap:v:314:y:2002:i:1:p:530-538
    DOI: 10.1016/S0378-4371(02)01046-4
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    Cited by:

    1. Mokshin, Anatolii V. & Khabibullin, Roman A., 2022. "Is there a one-to-one correspondence between interparticle interactions and physical properties of liquid?," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 608(P1).

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