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Application of the Kincaid-Cohen method to a binary gas-liquid system

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  • Meijer, Paul H.E.
  • Keskin, Mustafa

Abstract

In order to determine the phase diagram of the symmetric van der Waals model for gas-liquid binary systems we employ a method developed by Kincaid and Cohen for the molecular field model of the metamagnet. The method is based on an expansion in the dominant order parameter. The similarities and difference of the magnetic system and the van der Waals equation are discussed. It is shown how their method can be simplified and adapted to more general cases. The result is compared with the calculations of Korteweg and found to be in accordance with his results.

Suggested Citation

  • Meijer, Paul H.E. & Keskin, Mustafa, 1997. "Application of the Kincaid-Cohen method to a binary gas-liquid system," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 243(1), pages 47-57.
    • Handle: RePEc:eee:phsmap:v:243:y:1997:i:1:p:47-57
    DOI: 10.1016/S0378-4371(97)00271-9
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    References listed on IDEAS

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    1. Keskin, Mustafa & Ari, Mehmet & Meijer, Paul H.E, 1989. "Stable, metastable and unstable solutions of a spin-1 Ising system obtained by the molecular-field approximation and the path probability method," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 157(2), pages 1000-1017.
    2. Meijer, Paul H.E. & Stamm, W.C., 1978. "Phase diagram and critical points for a metamagnetic Ising model using constant coupling approximation," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 90(1), pages 77-96.
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