IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v236y1997i1p19-37.html
   My bibliography  Save this article

Cooperative molecular motions in water: The liquid-liquid critical point hypothesis

Author

Listed:
  • Stanley, H.E.
  • Cruz, L.
  • Harrington, S.T.
  • Poole, P.H.
  • Sastry, S.
  • Sciortino, F.
  • Starr, F.W.
  • Zhang, R.

Abstract

We discuss the hypothesis that, in addition to the known critical point in water (below which two fluid phases — a lower-density gas and a higher-density liquid — coexist), there exists a “second” critical point at low temperatures (below which two liquid phases — a higher-density liquid and a lower-density liquid — can coexits). We also discuss briefly some of the evidence relating to this hypothesis. This evidence is rather tentative at the present time, and is largely based on a growing number of computer simulations using the ST2 and TIP4P intermolecular potentials. We also discuss selected experimental results that are consistent with this hypothesis.

Suggested Citation

  • Stanley, H.E. & Cruz, L. & Harrington, S.T. & Poole, P.H. & Sastry, S. & Sciortino, F. & Starr, F.W. & Zhang, R., 1997. "Cooperative molecular motions in water: The liquid-liquid critical point hypothesis," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 236(1), pages 19-37.
    • Handle: RePEc:eee:phsmap:v:236:y:1997:i:1:p:19-37
    DOI: 10.1016/S0378-4371(96)00429-3
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0378437196004293
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000
    File URL: https://libkey.io/10.1016/S0378-4371(96)00429-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Stanley, H.E. & Buldyrev, S.V. & Canpolat, M. & Meyer, M. & Mishima, O. & Sadr-Lahijany, M.R. & Scala, A. & Starr, F.W., 1998. "The puzzling statistical physics of liquid water," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 257(1), pages 213-232.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:236:y:1997:i:1:p:19-37. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.