IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v231y1996i1p123-143.html
   My bibliography  Save this article

New perspectives in transport phenomena in electrolytes

Author

Listed:
  • Durand-Vidal, Serge
  • Turq, Pierre
  • Bernard, Olivier
  • Treiner, Claude
  • Blum, Lesser

Abstract

Using the Fuoss-Onsager theory we recently obtained simple expressions for the variation with concentration of the transport coefficients of electrolytes in aqueous solution. We studied self-diffusion, conductance of binary and ternary ionic mixtures, and micellar systems. We used in the formulation of the mean spherical approximation (MSA) pair correlation functions which yield explicit formulas in terms of the MSA inverse screening lenght Γ and the dynamical Debye-Falkenhagen lengths. It was found that the use of more accurate correlation functions, such as HNC, did not produce a significant improvement in the results. Associated electrolytes are also well described by a natural extension of this theory. Our simple expressions yield good agreement with the experiments for both unassociated and associated electrolytes.

Suggested Citation

  • Durand-Vidal, Serge & Turq, Pierre & Bernard, Olivier & Treiner, Claude & Blum, Lesser, 1996. "New perspectives in transport phenomena in electrolytes," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 231(1), pages 123-143.
    • Handle: RePEc:eee:phsmap:v:231:y:1996:i:1:p:123-143
    DOI: 10.1016/0378-4371(96)00083-0
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/0378437196000830
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000
    File URL: https://libkey.io/10.1016/0378-4371(96)00083-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. W. E. Paterson, 1975. "Social Democratic Parties Of The European Community," Journal of Common Market Studies, Wiley Blackwell, vol. 13(4), pages 415-418, June.
    2. Høye, J.S. & Bedeaux, D., 1977. "On the dielectric constant for a non-polar fluid, a comparison," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 87(2), pages 288-301.
    3. Cassell, E.J. & Lebowitz, M.D. & Wolter, D.W. & McCarroll, J.R., 1971. "Health and the urban environment. IX. The concept of the multiplex independent variable," American Journal of Public Health, American Public Health Association, vol. 61(12), pages 2348-2353.
    4. Evans, M.W. & Ferrario, M. & Grigolini, P., 1982. "Dielectric relaxation as a multiplicative stochastic process," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 111(1), pages 255-272.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Nieuwenhuizen, T.M., 1982. "A new approach to the problem of disordered harmonic chains," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 113(1), pages 173-202.
    2. Calvo, Miguel, 1991. "The character of the metastable phase singularities near the spinodal line," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 177(1), pages 339-344.
    3. Krause, R. & Arauz-Lara, J.L. & Nägele, G. & Ruiz-Estrada, H. & Medina-Noyola, M. & Weber, R. & Klein, R., 1991. "Statics and tracer-diffusion in binary suspensions of polystyrene spheres: experiment vs. theory," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 178(2), pages 241-279.
    4. Günther, C.C.A. & Rikvold, P.A. & Novotny, M.A., 1994. "Application of a constrained-transfer-matrix method to metastability in the d = 2 Ising ferromagnet," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 212(1), pages 194-229.
    5. Kobryn, A.E. & Morozov, V.G. & Omelyan, I.P. & Tokarchuk, M.V., 1996. "Enskog-Landau kinetic equation. Calculation of the transport coefficients for charged hard spheres," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 230(1), pages 189-201.
    6. Ruiz-Estrada, H. & Medina-Noyola, M. & Nägele, G., 1990. "Rescaled mean spherical approximation for colloidal mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 168(3), pages 919-941.
    7. Binder, K., 1986. "Decay of metastable and unstable states: Mechanisms, concepts and open problems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 140(1), pages 35-43.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:231:y:1996:i:1:p:123-143. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.