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Density profiles of associating fluid near a hard wall: PY/EMSA and HNC/EMSA singlet theory

Author

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  • Sokołowski, S.
  • Henderson, D.
  • Trokhymchuk, A.
  • Pizio, O.

Abstract

A two-component model of hard spheres with a spherically symmetric associative interaction between the particles of different species near a hard wall is studied by suing the integral equation method. It is shown that the extended mean spherical approximation for the bulk associating fluid in conjunction with the Percus-Yevick closure of the singlet level theory of inhomogeneous fluid leads to very good agreement of theoretical density profiles with simulation data for highly associated fluid at a high bulk density.

Suggested Citation

  • Sokołowski, S. & Henderson, D. & Trokhymchuk, A. & Pizio, O., 1995. "Density profiles of associating fluid near a hard wall: PY/EMSA and HNC/EMSA singlet theory," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 220(1), pages 24-32.
    • Handle: RePEc:eee:phsmap:v:220:y:1995:i:1:p:24-32
    DOI: 10.1016/0378-4371(95)00119-R
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    Cited by:

    1. Henderson, Douglas & Pizio, Orest & Sokolowski, Stefan & Trokhymchuk, Andrij, 1997. "The nonuniform Wertheim Ornstein-Zernike equation: Density profiles and pair correlation functions of a dimerizing hard sphere near a hard wall," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 244(1), pages 147-163.

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