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Traditional transport properties of CO

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  • Heck, E.L.
  • Dickinson, A.S.

Abstract

Classical trajectory rigid-rotor calculations using higher-order kinetic theory expressions for shear viscosity, diffusion, volume viscosity and thermal conductivity have been performed using the anisotropic ab initio potential energy hypersurface of van der Pol et al. for the temperature range between 77 K and 1500 K. Comparison with experiment shows differences less than 1.2% with the best shear viscosity measurements, consistency with the relative diffusion coefficient data, an underestimate by up to 30% of the volume viscosity values and agreement with the thermal conductivity data between 120 K and 200 K but differences increasing to 7% at 430 K.

Suggested Citation

  • Heck, E.L. & Dickinson, A.S., 1995. "Traditional transport properties of CO," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 217(1), pages 107-123.
    • Handle: RePEc:eee:phsmap:v:217:y:1995:i:1:p:107-123
    DOI: 10.1016/0378-4371(95)00099-S
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    References listed on IDEAS

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    1. Fleeter, R.D. & Kestin, J. & Paul, R. & Wakeham, W.A., 1981. "The thermal conductivity of mixtures of nitrogen with four noble gases at room temperature," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 108(2), pages 371-401.
    2. Vesovic, V. & Wakeham, W.A., 1993. "Practical, accurate expressions for the thermal conductivity of atom-diatom gas mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 201(4), pages 501-514.
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    4. Ross, M.J. & Vesovic, V. & Wakeham, W.A., 1992. "Alternative expressions for the thermal conductivity of dilute gas mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 183(4), pages 519-536.
    5. Imaishi, N. & Kestin, J. & Wakeham, W.A., 1984. "Thermal conductivity of two binary mixtures of gases of equal molecular weight," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 123(1), pages 50-71.
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