IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v214y1995i1p23-51.html
   My bibliography  Save this article

Inter-cluster scaling in two-dimensional colloidal aggregation

Author

Listed:
  • Earnshaw, J.C.
  • Robinson, D.J.

Abstract

Cluster-cluster aggregation has been studied experimentally in two-dimensional colloidal systems of moderately high area fraction. In the diffusion limited regime the system spontaneously exhibits ordering beyond the scale of the fractal aggregates, which persists into the gelled state. This ordering arises from an effective inter-cluster repulsion due to the mutually exclusive depletion zones surrounding each cluster. Various metrical and topological properties of the system indicate that this long-range order is stationary, apart from the inherent change of scale as the clusters grow. Topological correlations show that the inter-cluster self-organization is compatible with maximum entropy: the non-equilibrium system behaves as if it were in statistical equilibrium, and no physical forces are involved in the long-range order. For the reaction-limited case no such inter-cluster ordering is evident at any stage, the system is nonstationary, and the aggregation is governed by specific physical forces.

Suggested Citation

  • Earnshaw, J.C. & Robinson, D.J., 1995. "Inter-cluster scaling in two-dimensional colloidal aggregation," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 214(1), pages 23-51.
    • Handle: RePEc:eee:phsmap:v:214:y:1995:i:1:p:23-51
    DOI: 10.1016/0378-4371(94)00254-Q
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/037843719400254Q
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000
    File URL: https://libkey.io/10.1016/0378-4371(94)00254-Q?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Haw, M.D. & Poon, W.C.K. & Pusey, P.N., 1994. "Structure factors from cluster-cluster aggregation simulation at high concentration," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 208(1), pages 8-17.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Moncho-Jordá, A & Martı́nez-López, F & Hidalgo-Álvarez, R, 2000. "Simulations of aggregation in 2D. A study of kinetics, structure and topological properties," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 282(1), pages 50-64.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Poon, W.C.K. & Pirie, A.D. & Haw, M.D. & Pusey, P.N., 1997. "Non-equilibrium behaviour of colloid-polymer mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 235(1), pages 110-119.
    2. Löwen, Hartmut, 1997. "Possibilities of phase separation in colloidal suspensions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 235(1), pages 129-141.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:214:y:1995:i:1:p:23-51. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.