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Tilt stripe textures in Langmuir monolayers of fatty acids

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  • Schwartz, Daniel K.
  • Ruiz-Garcia, Jaime
  • Qiu, Xia
  • Selinger, Jonathan V.
  • Knobler, Charles M.

Abstract

Quantitative studies are described of striped textures in Langmuir monolayers of tetradecanoic and pentadecanoic acids. The textures, which are the result of modulations of the tilt azimuths of the molecules, have been visualized with polarized fluorescence microscopy. The stripe widths change with pressure and temperature. When the monolayer is compressed beyond a threshold pressure, the stripes become unstable and form a zig-zag pattern, which is likely the result of a crossover between the bend and splay elastic constants in the monolayer.

Suggested Citation

  • Schwartz, Daniel K. & Ruiz-Garcia, Jaime & Qiu, Xia & Selinger, Jonathan V. & Knobler, Charles M., 1994. "Tilt stripe textures in Langmuir monolayers of fatty acids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 204(1), pages 606-615.
    • Handle: RePEc:eee:phsmap:v:204:y:1994:i:1:p:606-615
    DOI: 10.1016/0378-4371(94)90449-9
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    Citations

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    Cited by:

    1. Knobler, Charles M., 1997. "Phase behavior, ordering and self-assembly in monolayers," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 236(1), pages 11-18.
    2. Liu, Cliff Z.-W. & Oppenheim, Irwin, 1997. "Reexamination of the mode-coupling scheme for the glass transition," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 235(3), pages 369-387.
    3. Bonn, Daniel & Pauchard, Ludovic & Shahidzadeh, Noushine & Meunier, Jacques, 1999. "Optical studies of low-dimensional phase transitions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 263(1), pages 78-94.
    4. Liu, Cliff Z.-W. & Oppenheim, Irwin, 1997. "Microscopic theory for hopping transport in glass-forming liquids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 247(1), pages 183-195.

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