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Onset of the dynamic glass transition in poly(n butyl methacrylate)

Author

Listed:
  • Beiner, M.
  • Garwe, F.
  • Hempel, E.
  • Schawe, J.
  • Schröter, K.
  • Schönhals, A.
  • Donth, E.

Abstract

Specific heat Cp, dynamic shear modulus G∗, and dielectric compliance ε∗ are measured in the splitting region a ↔ α + β of poly(n butyl methacrylate). The characteristic length of the glass transition is estimated from the calorimetric data to be about one nanometer before the breakdown of cooperativity between 15 and 21°C. The merging of the dielectric α and β traces is between 70 and 80°C, more than fifty degrees higher.

Suggested Citation

  • Beiner, M. & Garwe, F. & Hempel, E. & Schawe, J. & Schröter, K. & Schönhals, A. & Donth, E., 1993. "Onset of the dynamic glass transition in poly(n butyl methacrylate)," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 201(1), pages 72-78.
    • Handle: RePEc:eee:phsmap:v:201:y:1993:i:1:p:72-78
    DOI: 10.1016/0378-4371(93)90401-O
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    References listed on IDEAS

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    1. Schick, M., 1991. "Lattice model of amphiphilic systems: A review," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 172(1), pages 200-208.
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