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A new surface phase in liquid normal-alkanes

Author

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  • Wu, X.Z.
  • Ocko, B.M.
  • Sirota, E.B.
  • Sinha, S.K.
  • Deutsch, M.

Abstract

A new surface phase is found in liquid normal-alkanes. X-ray and surface tension measurements show the formation of a crystalline monolayer on the surface of the liquid at temperatures up to 3°C above the bulk solidification temperature, Tf. The molecules in the monolayer are hexagonally packed and oriented normal to the surface. A single solid monolayer persists down to Tf, thus exhibiting a very limited partial wetting. The new surface phase is obtained only for chain lengths 14

Suggested Citation

  • Wu, X.Z. & Ocko, B.M. & Sirota, E.B. & Sinha, S.K. & Deutsch, M., 1993. "A new surface phase in liquid normal-alkanes," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 200(1), pages 751-758.
    • Handle: RePEc:eee:phsmap:v:200:y:1993:i:1:p:751-758
    DOI: 10.1016/0378-4371(93)90583-P
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