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Statistical mechanical theory of polar fluids for all densities

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  • Zakharov, A.V.
  • Aero, E.L.

Abstract

We present results for the structure and thermodynamics of a polar fluid obtained from a recently developed theory which is based on the method of conditional distribution. Within the framework of the method the concept of the average force potentials is used to develop a truncation procedure for an arbitrary equation of the chain. A closed system of integral equations for the average force potential is formulated. The Helmholtz free energy, the pressure, structural properties and the static dielectric constant are calculated in terms of the binary distribution function. We compare our results with experimental data and find that the theory gives realistic results. Comparisons are also made for self-diffusion coefficients obtained from molecular dynamics simulations.

Suggested Citation

  • Zakharov, A.V. & Aero, E.L., 1989. "Statistical mechanical theory of polar fluids for all densities," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 160(2), pages 157-165.
    • Handle: RePEc:eee:phsmap:v:160:y:1989:i:2:p:157-165
    DOI: 10.1016/0378-4371(89)90413-5
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    References listed on IDEAS

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    1. Homme, Henry A. & Simmons, Richard L., 1965. "Planning Agricultural Processing for the South: Butter and Milk Powder Manufacturing Costs," Archive 259584, North Carolina State University, Department of Agricultural and Resource Economics.
    2. Vikhrenko, V.S. & Bokun, G.S., 1978. "Truncation procedure for high order reduced distribution functions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 90(3), pages 587-596.
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