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Statistical mechanics of two-dimensional coulomb systems

Author

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  • Perram, John W.
  • de Leeuw, Simon W.

Abstract

The statistical mechanics of systems acting via two-dimensional charge-charge and dipole-dipole interactions is studied in periodic boundary conditions. The two-dimensional lattice theta-function transformation is obtained and the sum shown to contain a polarization correction to the Ewald sum, analogous to that found in three dimensions. Using a different approach, these sums are evaluated in closed form, for bodies of arbitrary shape. The methodology for the computer simulation of two dimensional dielectrics is discussed and the two-dimensional analogue of a generalized Kirkwood-Clausius-Mosotti-Debye formula derived.

Suggested Citation

  • Perram, John W. & de Leeuw, Simon W., 1981. "Statistical mechanics of two-dimensional coulomb systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 109(1), pages 237-250.
  • Handle: RePEc:eee:phsmap:v:109:y:1981:i:1:p:237-250
    DOI: 10.1016/0378-4371(81)90047-9
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