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Liquid-crystalline ordering in the solution of long persistent chains

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  • Khokhlov, A.R.
  • Semenov, A.N.

Abstract

The orientational ordering in the solution of long persistent macromolecules is studied by means of the Onsager method. It is shown that the liquid-crystalline transition occurs at significantly higher concentrations and that the order parameter at the transition point is much smaller than for the model of freely-jointed segments. It is concluded that the orientational ordering in the solutions of semiflexible chains depends essentially on the flexibility distribution along the chain contour.

Suggested Citation

  • Khokhlov, A.R. & Semenov, A.N., 1981. "Liquid-crystalline ordering in the solution of long persistent chains," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 108(2), pages 546-556.
  • Handle: RePEc:eee:phsmap:v:108:y:1981:i:2:p:546-556
    DOI: 10.1016/0378-4371(81)90148-5
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    References listed on IDEAS

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    1. Alessandro Roncaglia, 1979. "Sraffa and the Reconstruction of Political Economy," Challenge, Taylor & Francis Journals, vol. 21(6), pages 48-53, January.
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    1. Khokhlov, A.R. & Semenov, A.N., 1982. "Liquid-crystalline ordering in the solution of partially flexible macromolecules," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 112(3), pages 605-614.
    2. Rill, Randolph L. & Strzelecka, Teresa E. & Davidson, Michael W. & Van Winkle, David H., 1991. "Ordered phases in concentrated DNA solutions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 176(1), pages 87-116.

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